Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization

Prussian blue analogues CoTCNi/HCCr and CoTCNi/HCCr/CNTs were stoichiometrically prepared by Co-precipitation method and the thin films deposited onto glass substrates via spin coater. XRD, Raman spectroscopy, EDX, SEM, and TEM techniques have been used to analyze the samples. The findings revealed...

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Main Author: Elsayed Elgazzar
Format: Article
Language:English
Published: IOP Publishing 2020-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/aba0ea
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author Elsayed Elgazzar
author_facet Elsayed Elgazzar
author_sort Elsayed Elgazzar
collection DOAJ
description Prussian blue analogues CoTCNi/HCCr and CoTCNi/HCCr/CNTs were stoichiometrically prepared by Co-precipitation method and the thin films deposited onto glass substrates via spin coater. XRD, Raman spectroscopy, EDX, SEM, and TEM techniques have been used to analyze the samples. The findings revealed the fabricated nanostructured materials of face-centered cubic (FCC) phase, in spherical shape decorated by CNTs. Transmittance ( T %) and reflectance ( R %) spectra of the thin films were measured in the wavelength range from 200 to 900 nm. The films exhibit high transparency more than 70% within the visible spectrum. Besides, the optical band gap $({E}_{g})$ was estimated showing blue shift caused by CNTs support.
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spelling doaj.art-681d8f2678fb4472973c2acbaf0eb7cc2023-08-09T16:16:42ZengIOP PublishingMaterials Research Express2053-15912020-01-017707500410.1088/2053-1591/aba0eaPrussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterizationElsayed Elgazzar0https://orcid.org/0000-0001-9927-9846Department of Physics, Faculty of Science, Suez Canal University , Ismailia, EgyptPrussian blue analogues CoTCNi/HCCr and CoTCNi/HCCr/CNTs were stoichiometrically prepared by Co-precipitation method and the thin films deposited onto glass substrates via spin coater. XRD, Raman spectroscopy, EDX, SEM, and TEM techniques have been used to analyze the samples. The findings revealed the fabricated nanostructured materials of face-centered cubic (FCC) phase, in spherical shape decorated by CNTs. Transmittance ( T %) and reflectance ( R %) spectra of the thin films were measured in the wavelength range from 200 to 900 nm. The films exhibit high transparency more than 70% within the visible spectrum. Besides, the optical band gap $({E}_{g})$ was estimated showing blue shift caused by CNTs support.https://doi.org/10.1088/2053-1591/aba0eaPrussian blue analoguesco-precipitationcrystal structureoptical conductivity
spellingShingle Elsayed Elgazzar
Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
Materials Research Express
Prussian blue analogues
co-precipitation
crystal structure
optical conductivity
title Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
title_full Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
title_fullStr Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
title_full_unstemmed Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
title_short Prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by CNTs: structural, morphological, optical characterization
title_sort prussian blue analogue cobalt tetracyanonickelate hexacyanochromate decorated by cnts structural morphological optical characterization
topic Prussian blue analogues
co-precipitation
crystal structure
optical conductivity
url https://doi.org/10.1088/2053-1591/aba0ea
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