Summary: | In the title compound, C14H13ClN2O5S2, the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intramolecular C—H...O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(20) loops. A second N—H...O hydrogen bond links the dimers into (101) layers.
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