N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide
In the title compound, C14H13ClN2O5S2, the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812023434 |
| _version_ | 1819280234222977024 |
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| author | Islam Ullah Khan Ejaz Sidra Farid William T. A. Harrison |
| author_facet | Islam Ullah Khan Ejaz Sidra Farid William T. A. Harrison |
| author_sort | Islam Ullah Khan |
| collection | DOAJ |
| description | In the title compound, C14H13ClN2O5S2, the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intramolecular C—H...O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(20) loops. A second N—H...O hydrogen bond links the dimers into (101) layers. |
| first_indexed | 2024-12-24T00:40:33Z |
| format | Article |
| id | doaj.art-6831e04ac3e64fa6ba60bb9502d2f255 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:40:33Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6831e04ac3e64fa6ba60bb9502d2f2552022-12-21T17:23:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1913o191310.1107/S1600536812023434N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamideIslam Ullah KhanEjazSidra FaridWilliam T. A. HarrisonIn the title compound, C14H13ClN2O5S2, the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intramolecular C—H...O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(20) loops. A second N—H...O hydrogen bond links the dimers into (101) layers.http://scripts.iucr.org/cgi-bin/paper?S1600536812023434 |
| spellingShingle | Islam Ullah Khan Ejaz Sidra Farid William T. A. Harrison N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide Acta Crystallographica Section E |
| title | N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
| title_full | N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
| title_fullStr | N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
| title_full_unstemmed | N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
| title_short | N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
| title_sort | n 4 4 chlorobenzenesulfonamido phenylsulfonyl acetamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812023434 |
| work_keys_str_mv | AT islamullahkhan n44chlorobenzenesulfonamidophenylsulfonylacetamide AT ejaz n44chlorobenzenesulfonamidophenylsulfonylacetamide AT sidrafarid n44chlorobenzenesulfonamidophenylsulfonylacetamide AT williamtaharrison n44chlorobenzenesulfonamidophenylsulfonylacetamide |