Rheological behavior of rosin-sourced anhydride bio-epoxy resin system

Viscosity is the main rheology parameter of thermosetting resin matrix processing, which is an important factor effecting processing performance. The viscosity-temperature curves at dynamic states and viscosity-time curves at stead state were measured by cone-plate rotate viscosimeter, and the rheol...

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Main Authors: ZHANG Xufeng, LI Dihui, QI Xi, TONG Jifeng, YI Xiaosu
Format: Article
Language:zho
Published: Journal of Aeronautical Materials 2021-04-01
Series:Journal of Aeronautical Materials
Subjects:
Online Access:http://jam.biam.ac.cn/article/doi/10.11868/j.issn.1005-5053.2019.000169
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author ZHANG Xufeng
LI Dihui
QI Xi
TONG Jifeng
YI Xiaosu
author_facet ZHANG Xufeng
LI Dihui
QI Xi
TONG Jifeng
YI Xiaosu
author_sort ZHANG Xufeng
collection DOAJ
description Viscosity is the main rheology parameter of thermosetting resin matrix processing, which is an important factor effecting processing performance. The viscosity-temperature curves at dynamic states and viscosity-time curves at stead state were measured by cone-plate rotate viscosimeter, and the rheology property of bio-based resin system based on rosin-sourced anhydride curing agent was studied according to the optimization improved six parameter dual-arrhenius equation. Two kinds of rheology models were established by fitting reaction rate constant K and pre-exponential factor A according to the exponential or logarithm viscosity relative equation, respectively. The rheology model based on logarithm viscosity relative equation simulation was in good agreement with experimental data than exponential viscosity relative equation fitting. The rheology model demonstrated the law of viscosity change at different processing conditions, which provided necessary scientific basis for processing parameter optimization.
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spelling doaj.art-686edf8195f74af7bbbf895ec5e80f3e2022-12-21T19:44:06ZzhoJournal of Aeronautical MaterialsJournal of Aeronautical Materials1005-50531005-50532021-04-014129810410.11868/j.issn.1005-5053.2019.0001692019-0169Rheological behavior of rosin-sourced anhydride bio-epoxy resin systemZHANG Xufeng0LI Dihui1QI Xi2TONG Jifeng3YI Xiaosu4Beijing Municipal Engineering Laboratory of Green Composites,ACC(Beijing)Science and Technology Co.,Ltd,Beijing 101300,ChinaBeijing Municipal Engineering Laboratory of Green Composites,ACC(Beijing)Science and Technology Co.,Ltd,Beijing 101300,ChinaBeijing Municipal Engineering Laboratory of Green Composites,ACC(Beijing)Science and Technology Co.,Ltd,Beijing 101300,ChinaBeijing Municipal Engineering Laboratory of Green Composites,ACC(Beijing)Science and Technology Co.,Ltd,Beijing 101300,ChinaBeijing Municipal Engineering Laboratory of Green Composites,ACC(Beijing)Science and Technology Co.,Ltd,Beijing 101300,ChinaViscosity is the main rheology parameter of thermosetting resin matrix processing, which is an important factor effecting processing performance. The viscosity-temperature curves at dynamic states and viscosity-time curves at stead state were measured by cone-plate rotate viscosimeter, and the rheology property of bio-based resin system based on rosin-sourced anhydride curing agent was studied according to the optimization improved six parameter dual-arrhenius equation. Two kinds of rheology models were established by fitting reaction rate constant K and pre-exponential factor A according to the exponential or logarithm viscosity relative equation, respectively. The rheology model based on logarithm viscosity relative equation simulation was in good agreement with experimental data than exponential viscosity relative equation fitting. The rheology model demonstrated the law of viscosity change at different processing conditions, which provided necessary scientific basis for processing parameter optimization.http://jam.biam.ac.cn/article/doi/10.11868/j.issn.1005-5053.2019.000169bio-basedepoxy resinrheology modelfitting research
spellingShingle ZHANG Xufeng
LI Dihui
QI Xi
TONG Jifeng
YI Xiaosu
Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
Journal of Aeronautical Materials
bio-based
epoxy resin
rheology model
fitting research
title Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
title_full Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
title_fullStr Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
title_full_unstemmed Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
title_short Rheological behavior of rosin-sourced anhydride bio-epoxy resin system
title_sort rheological behavior of rosin sourced anhydride bio epoxy resin system
topic bio-based
epoxy resin
rheology model
fitting research
url http://jam.biam.ac.cn/article/doi/10.11868/j.issn.1005-5053.2019.000169
work_keys_str_mv AT zhangxufeng rheologicalbehaviorofrosinsourcedanhydridebioepoxyresinsystem
AT lidihui rheologicalbehaviorofrosinsourcedanhydridebioepoxyresinsystem
AT qixi rheologicalbehaviorofrosinsourcedanhydridebioepoxyresinsystem
AT tongjifeng rheologicalbehaviorofrosinsourcedanhydridebioepoxyresinsystem
AT yixiaosu rheologicalbehaviorofrosinsourcedanhydridebioepoxyresinsystem