The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer
In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epox...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Sciendo
2018-12-01
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| Series: | Polish Journal of Chemical Technology |
| Subjects: | |
| Online Access: | https://doi.org/10.2478/pjct-2018-0048 |
| _version_ | 1818696025073778688 |
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| author | Song Fei Xia Haoyu Jia Puyou Zhang Meng Hu Lihong Zhou Yonghong |
| author_facet | Song Fei Xia Haoyu Jia Puyou Zhang Meng Hu Lihong Zhou Yonghong |
| author_sort | Song Fei |
| collection | DOAJ |
| description | In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FTIR and 1H-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with DOP. The results showed that EACO improved polyvinyl-chloride (PVC) plasticization performance and reduced Tg from 81.06°C to 1.40°C. Plasticized PVC materials with EACO showed similar mechanical properties and better thermal stability than DOP. EACO had better volatility stabilities, migration and solvent extraction in PVC than DOP. EACO can be used to replace DOP to prepare soft films. |
| first_indexed | 2024-12-17T13:54:48Z |
| format | Article |
| id | doaj.art-6881099e5e614807801dc1048c8e6eae |
| institution | Directory Open Access Journal |
| issn | 1899-4741 |
| language | English |
| last_indexed | 2024-12-17T13:54:48Z |
| publishDate | 2018-12-01 |
| publisher | Sciendo |
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| series | Polish Journal of Chemical Technology |
| spelling | doaj.art-6881099e5e614807801dc1048c8e6eae2022-12-21T21:45:57ZengSciendoPolish Journal of Chemical Technology1899-47412018-12-01204131910.2478/pjct-2018-0048pjct-2018-0048The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main PlasticizerSong Fei0Xia Haoyu1Jia Puyou2Zhang Meng3Hu Lihong4Zhou Yonghong5Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road,Nanjing210042, P.R. ChinaNanjing Tech University, College of Chemical Engineering, 30 Pu Zhu Road,Nanjing211800, P.R. ChinaChinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road,Nanjing210042, P.R. ChinaChinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road,Nanjing210042, P.R. ChinaChinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road,Nanjing210042, P.R. ChinaChinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road,Nanjing210042, P.R. ChinaIn this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FTIR and 1H-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with DOP. The results showed that EACO improved polyvinyl-chloride (PVC) plasticization performance and reduced Tg from 81.06°C to 1.40°C. Plasticized PVC materials with EACO showed similar mechanical properties and better thermal stability than DOP. EACO had better volatility stabilities, migration and solvent extraction in PVC than DOP. EACO can be used to replace DOP to prepare soft films.https://doi.org/10.2478/pjct-2018-0048castor oilpoly(vinyl chloride)epoxy plasticizerthermal propertymigration resistance |
| spellingShingle | Song Fei Xia Haoyu Jia Puyou Zhang Meng Hu Lihong Zhou Yonghong The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer Polish Journal of Chemical Technology castor oil poly(vinyl chloride) epoxy plasticizer thermal property migration resistance |
| title | The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer |
| title_full | The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer |
| title_fullStr | The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer |
| title_full_unstemmed | The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer |
| title_short | The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer |
| title_sort | effects of epoxidized acrylated castor oil eaco on soft poly vinyl chloride films as a main plasticizer |
| topic | castor oil poly(vinyl chloride) epoxy plasticizer thermal property migration resistance |
| url | https://doi.org/10.2478/pjct-2018-0048 |
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