Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber

Natural fibers have, in past decades, been increasingly used as reinforcement of polymer matrix composites in substitution for synthetic fibers. This work presents a comparative study on the mechanical properties of both epoxy and polyester composites reinforced with promising hemp fiber. The compar...

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Main Authors: Anna Carolina C. Neves, Lázaro A. Rohen, Dhyemila P. Mantovani, Juliana P.R.G. Carvalho, Carlos Maurício F. Vieira, Felipe P.D. Lopes, Noan Tonini Simonassi, Fernanda S. da Luz, Sergio N. Monteiro
Format: Article
Language:English
Published: Elsevier 2020-03-01
Series:Journal of Materials Research and Technology
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785419305708
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author Anna Carolina C. Neves
Lázaro A. Rohen
Dhyemila P. Mantovani
Juliana P.R.G. Carvalho
Carlos Maurício F. Vieira
Felipe P.D. Lopes
Noan Tonini Simonassi
Fernanda S. da Luz
Sergio N. Monteiro
author_facet Anna Carolina C. Neves
Lázaro A. Rohen
Dhyemila P. Mantovani
Juliana P.R.G. Carvalho
Carlos Maurício F. Vieira
Felipe P.D. Lopes
Noan Tonini Simonassi
Fernanda S. da Luz
Sergio N. Monteiro
author_sort Anna Carolina C. Neves
collection DOAJ
description Natural fibers have, in past decades, been increasingly used as reinforcement of polymer matrix composites in substitution for synthetic fibers. This work presents a comparative study on the mechanical properties of both epoxy and polyester composites reinforced with promising hemp fiber. The comparison would allow which of these thermoset matrices is more adequate for novel biocomposites to be used in technological applications. Amounts of 10, 20 and 30 vol% of continuous and aligned hemp fibers were mixed with either epoxy or polyester inside steel molds kept under pressure and cured for 24 h at room temperature. Plain epoxy and polyester plates were also fabricated for control samples. Basic characterization by Fourier transform infrared spectroscopy was preliminarly performed. Mechanical properties were obtained in flexural and tensile tests according to ASTM standards. Results were statistically compared by ANOVA and Tukey tests. Fracture was analyzed by scanning electron microscopy. For higher amount, 30 vol% of reinforcing hemp fiber, the epoxy composites disclosed superior strength than those of polyester composites. Indeed, for epoxy composites the flexural and tensile strength, 76.7 and 50.5 MPa, respectively, are higher than corresponding 49.1 and 25.4 MPa, respectively, for polyester composites. As for the elastic modulus, the flexural of 30 vol% hemp fiber/epoxy composites, 3.8 GPa, was superior to 30 vol% hemp fiber/polyester, with 1.2 GPa. These results indicate a potential application of hemp fiber/epoxy composites as part of multilayered armor systems for personal ballistic protection. Keywords: Hemp fiber, Epoxy composite, Polyester composite, Mechanical properties
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spelling doaj.art-6887c1c407a74a6995c95f06eb21ded52022-12-22T03:53:56ZengElsevierJournal of Materials Research and Technology2238-78542020-03-019212961304Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiberAnna Carolina C. Neves0Lázaro A. Rohen1Dhyemila P. Mantovani2Juliana P.R.G. Carvalho3Carlos Maurício F. Vieira4Felipe P.D. Lopes5Noan Tonini Simonassi6Fernanda S. da Luz7Sergio N. Monteiro8State University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, Brazil; Corresponding author.State University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilState University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilState University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilState University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilState University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilState University of the North of Rio de Janeiro Darcy Ribeiro – UENF, Advanced Materials Laboratory, Av Alberto Lamego, 2000, CEP 28013-602, Campos dos Goytacazes, RJ, BrazilMilitary Institute of Engineering - IME, Department of Materials Science, Praça General Tibúrcio, 80, Praia Vermelha, Urca, RJ, CEP 22290-270, Urca, Rio de Janeiro, RJ, BrazilMilitary Institute of Engineering - IME, Department of Materials Science, Praça General Tibúrcio, 80, Praia Vermelha, Urca, RJ, CEP 22290-270, Urca, Rio de Janeiro, RJ, BrazilNatural fibers have, in past decades, been increasingly used as reinforcement of polymer matrix composites in substitution for synthetic fibers. This work presents a comparative study on the mechanical properties of both epoxy and polyester composites reinforced with promising hemp fiber. The comparison would allow which of these thermoset matrices is more adequate for novel biocomposites to be used in technological applications. Amounts of 10, 20 and 30 vol% of continuous and aligned hemp fibers were mixed with either epoxy or polyester inside steel molds kept under pressure and cured for 24 h at room temperature. Plain epoxy and polyester plates were also fabricated for control samples. Basic characterization by Fourier transform infrared spectroscopy was preliminarly performed. Mechanical properties were obtained in flexural and tensile tests according to ASTM standards. Results were statistically compared by ANOVA and Tukey tests. Fracture was analyzed by scanning electron microscopy. For higher amount, 30 vol% of reinforcing hemp fiber, the epoxy composites disclosed superior strength than those of polyester composites. Indeed, for epoxy composites the flexural and tensile strength, 76.7 and 50.5 MPa, respectively, are higher than corresponding 49.1 and 25.4 MPa, respectively, for polyester composites. As for the elastic modulus, the flexural of 30 vol% hemp fiber/epoxy composites, 3.8 GPa, was superior to 30 vol% hemp fiber/polyester, with 1.2 GPa. These results indicate a potential application of hemp fiber/epoxy composites as part of multilayered armor systems for personal ballistic protection. Keywords: Hemp fiber, Epoxy composite, Polyester composite, Mechanical propertieshttp://www.sciencedirect.com/science/article/pii/S2238785419305708
spellingShingle Anna Carolina C. Neves
Lázaro A. Rohen
Dhyemila P. Mantovani
Juliana P.R.G. Carvalho
Carlos Maurício F. Vieira
Felipe P.D. Lopes
Noan Tonini Simonassi
Fernanda S. da Luz
Sergio N. Monteiro
Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
Journal of Materials Research and Technology
title Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
title_full Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
title_fullStr Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
title_full_unstemmed Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
title_short Comparative mechanical properties between biocomposites of Epoxy and polyester matrices reinforced by hemp fiber
title_sort comparative mechanical properties between biocomposites of epoxy and polyester matrices reinforced by hemp fiber
url http://www.sciencedirect.com/science/article/pii/S2238785419305708
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