Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia

In 2001-2007 aerosols were measured in the coastal zone (11 campaigns) and over the open waters of the Gdańsk Basin (southern Baltic) (5 campaigns). The marine aerosols contained nitrogen and sulphur compounds, which increased their acidity. This situation intensified during the cool months of the y...

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Main Authors: Anita Urszula Lewandowska, Lucyna Mirosława Falkowska
Format: Article
Language:English
Published: Elsevier 2013-05-01
Series:Oceanologia
Subjects:
Online Access:http://www.iopan.gda.pl/oceanologia/55_2.html#A2
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author Anita Urszula Lewandowska
Lucyna Mirosława Falkowska
author_facet Anita Urszula Lewandowska
Lucyna Mirosława Falkowska
author_sort Anita Urszula Lewandowska
collection DOAJ
description In 2001-2007 aerosols were measured in the coastal zone (11 campaigns) and over the open waters of the Gdańsk Basin (southern Baltic) (5 campaigns). The marine aerosols contained nitrogen and sulphur compounds, which increased their acidity. This situation intensified during the cool months of the year, when fossil fuel emissions were higher, proportionate to energy and heat requirements. Irrespective of the season, these acidic aerosols were neutralized in the reaction with sea salt. The likelihood of sodium nitrate being formed increased at air humidities &gt; 80% and nitrate concentrations &gt; 30 nmol m<sup>-3</sup>. Sodium sulphate was present in aerosols mostly in autumn and winter, with northerly advection, and at the highest wind speeds. The excess of free ammonia resulted in the formation of ammonium sulphate and ammonium nitrate in aerosols over the southern Baltic.
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spelling doaj.art-68bc5d664c4941a7ad5c53ad8d5495432022-12-22T00:24:35ZengElsevierOceanologia0078-32342013-05-0155229931810.5697/oc.55-2.299 Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammoniaAnita Urszula LewandowskaLucyna Mirosława FalkowskaIn 2001-2007 aerosols were measured in the coastal zone (11 campaigns) and over the open waters of the Gdańsk Basin (southern Baltic) (5 campaigns). The marine aerosols contained nitrogen and sulphur compounds, which increased their acidity. This situation intensified during the cool months of the year, when fossil fuel emissions were higher, proportionate to energy and heat requirements. Irrespective of the season, these acidic aerosols were neutralized in the reaction with sea salt. The likelihood of sodium nitrate being formed increased at air humidities &gt; 80% and nitrate concentrations &gt; 30 nmol m<sup>-3</sup>. Sodium sulphate was present in aerosols mostly in autumn and winter, with northerly advection, and at the highest wind speeds. The excess of free ammonia resulted in the formation of ammonium sulphate and ammonium nitrate in aerosols over the southern Baltic.http://www.iopan.gda.pl/oceanologia/55_2.html#A2Sea saltAcid aerosolsNeutralizationCoastal zone
spellingShingle Anita Urszula Lewandowska
Lucyna Mirosława Falkowska
Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
Oceanologia
Sea salt
Acid aerosols
Neutralization
Coastal zone
title Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
title_full Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
title_fullStr Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
title_full_unstemmed Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
title_short Sea salt in aerosols over the southern Baltic. Part 2. The neutralizing properties of sea salt and ammonia
title_sort sea salt in aerosols over the southern baltic part 2 the neutralizing properties of sea salt and ammonia
topic Sea salt
Acid aerosols
Neutralization
Coastal zone
url http://www.iopan.gda.pl/oceanologia/55_2.html#A2
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