Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-p...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808039949 |
| _version_ | 1818997442588180480 |
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| author | Huanyu Liu Dongsheng Shen |
| author_facet | Huanyu Liu Dongsheng Shen |
| author_sort | Huanyu Liu |
| collection | DOAJ |
| description | There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions. |
| first_indexed | 2024-12-20T21:45:42Z |
| format | Article |
| id | doaj.art-68d577036cc44446aa0e4f56cf82e20d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:45:42Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-68d577036cc44446aa0e4f56cf82e20d2022-12-21T19:25:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m8m810.1107/S1600536808039949Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvateHuanyu LiuDongsheng ShenThere are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions.http://scripts.iucr.org/cgi-bin/paper?S1600536808039949 |
| spellingShingle | Huanyu Liu Dongsheng Shen Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate Acta Crystallographica Section E |
| title | Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate |
| title_full | Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate |
| title_fullStr | Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate |
| title_full_unstemmed | Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate |
| title_short | Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate |
| title_sort | dichlorido 2 diphenylphosphino phenyliminomethyl ferrocene 954 2n p palladium ii dichloromethane hemisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808039949 |
| work_keys_str_mv | AT huanyuliu dichlorido2diphenylphosphinophenyliminomethylferrocene9542nppalladiumiidichloromethanehemisolvate AT dongshengshen dichlorido2diphenylphosphinophenyliminomethylferrocene9542nppalladiumiidichloromethanehemisolvate |