5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide
In the title compound, C25H17ClF3N3O2S, the five-membered 1,3-thiazolidine ring adopts a twist conformation. The three F atoms of the CF3 group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ri...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812039347 |
| _version_ | 1818959952331407360 |
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| author | Mehmet Akkurt İsmail Çelik Füsun Kazan Gürbüzel Sumru Özkırımlı Orhan Büyükgüngör |
| author_facet | Mehmet Akkurt İsmail Çelik Füsun Kazan Gürbüzel Sumru Özkırımlı Orhan Büyükgüngör |
| author_sort | Mehmet Akkurt |
| collection | DOAJ |
| description | In the title compound, C25H17ClF3N3O2S, the five-membered 1,3-thiazolidine ring adopts a twist conformation. The three F atoms of the CF3 group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ring system, the 1H-pyrrole ring forms a dihedral angle of 4.7 (2)° with the benzene ring, while it is twisted at an angle of 46.5 (2)° with respect to the attached phenyl ring. The dihedral angle between the phenyl and trifluoromethyl-substituted benzene rings is 56.0 (2)°. In the crystal, N—H...O hydrogen bonds connect the molecules into a three-dimensional network. In addition, weak C—H...O hydrogen bonds and weak C—H...π interactions are observed. |
| first_indexed | 2024-12-20T11:49:49Z |
| format | Article |
| id | doaj.art-68d903205a454e81a2baf4fec0781ed3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:49:49Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-68d903205a454e81a2baf4fec0781ed32022-12-21T19:41:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2969o297010.1107/S16005368120393475-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamideMehmet Akkurtİsmail ÇelikFüsun Kazan GürbüzelSumru ÖzkırımlıOrhan BüyükgüngörIn the title compound, C25H17ClF3N3O2S, the five-membered 1,3-thiazolidine ring adopts a twist conformation. The three F atoms of the CF3 group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ring system, the 1H-pyrrole ring forms a dihedral angle of 4.7 (2)° with the benzene ring, while it is twisted at an angle of 46.5 (2)° with respect to the attached phenyl ring. The dihedral angle between the phenyl and trifluoromethyl-substituted benzene rings is 56.0 (2)°. In the crystal, N—H...O hydrogen bonds connect the molecules into a three-dimensional network. In addition, weak C—H...O hydrogen bonds and weak C—H...π interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812039347 |
| spellingShingle | Mehmet Akkurt İsmail Çelik Füsun Kazan Gürbüzel Sumru Özkırımlı Orhan Büyükgüngör 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide Acta Crystallographica Section E |
| title | 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide |
| title_full | 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide |
| title_fullStr | 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide |
| title_full_unstemmed | 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide |
| title_short | 5-Chloro-N-{4-oxo-2-[4-(trifluoromethyl)phenyl]-1,3-thiazolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide |
| title_sort | 5 chloro n 4 oxo 2 4 trifluoromethyl phenyl 1 3 thiazolidin 3 yl 3 phenyl 1h indole 2 carboxamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812039347 |
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