Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H<sub>2</sub>O}<sub>n</sub> chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MO...
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MDPI AG
2023-02-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/4/1846 |
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| author | Estitxu Echenique-Errandonea Sara Rojas Javier Cepeda Duane Choquesillo-Lazarte Antonio Rodríguez-Diéguez José M. Seco |
| author_facet | Estitxu Echenique-Errandonea Sara Rojas Javier Cepeda Duane Choquesillo-Lazarte Antonio Rodríguez-Diéguez José M. Seco |
| author_sort | Estitxu Echenique-Errandonea |
| collection | DOAJ |
| description | As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H<sub>2</sub>O}<sub>n</sub> chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (<i>ac</i>) signals under zero direct current (<i>dc</i>) magnetic field, whereas single-molecule magnet behaviour is achieved when Co<sup>II</sup> ions are diluted in a Zn<sup>II</sup> based matrix. Interestingly, this strategy renders a bifunctional [Co<sub>x</sub>Zn<sub>1-x</sub>L]<sub>n</sub> material that is also characterized by a strong photoluminescent emitting capacity. |
| first_indexed | 2024-03-11T08:21:02Z |
| format | Article |
| id | doaj.art-68f20fee6029406b96c52572b2a51d35 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T08:21:02Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-68f20fee6029406b96c52572b2a51d352023-11-16T22:24:01ZengMDPI AGMolecules1420-30492023-02-01284184610.3390/molecules28041846Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal IonsEstitxu Echenique-Errandonea0Sara Rojas1Javier Cepeda2Duane Choquesillo-Lazarte3Antonio Rodríguez-Diéguez4José M. Seco5Applied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, SpainInorganic Chemistry Department, Faculty of Sciences, University of Granada, Avda. Fuentenueva S/N, 18002 Granada, SpainApplied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, SpainLaboratory for Crystallographic Studies IACT, CSIC-UGR, Av. Las Palmeras n°4, 18100 Granada, SpainInorganic Chemistry Department, Faculty of Sciences, University of Granada, Avda. Fuentenueva S/N, 18002 Granada, SpainApplied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, SpainAs a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H<sub>2</sub>O}<sub>n</sub> chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (<i>ac</i>) signals under zero direct current (<i>dc</i>) magnetic field, whereas single-molecule magnet behaviour is achieved when Co<sup>II</sup> ions are diluted in a Zn<sup>II</sup> based matrix. Interestingly, this strategy renders a bifunctional [Co<sub>x</sub>Zn<sub>1-x</sub>L]<sub>n</sub> material that is also characterized by a strong photoluminescent emitting capacity.https://www.mdpi.com/1420-3049/28/4/1846metal-organic frameworkcobalt-zinc bifunctionalityinduced molecular magnetismphotoluminescent properties |
| spellingShingle | Estitxu Echenique-Errandonea Sara Rojas Javier Cepeda Duane Choquesillo-Lazarte Antonio Rodríguez-Diéguez José M. Seco Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions Molecules metal-organic framework cobalt-zinc bifunctionality induced molecular magnetism photoluminescent properties |
| title | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions |
| title_full | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions |
| title_fullStr | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions |
| title_full_unstemmed | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions |
| title_short | Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions |
| title_sort | slow magnetic relaxation and modulated photoluminescent emission of coordination polymer based on 3 amino 4 hydroxybenzoate zn and co metal ions |
| topic | metal-organic framework cobalt-zinc bifunctionality induced molecular magnetism photoluminescent properties |
| url | https://www.mdpi.com/1420-3049/28/4/1846 |
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