Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
In this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst f...
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Format: | Article |
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Growing Science
2018-11-01
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Series: | Current Chemistry Letters |
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Online Access: | http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdf |
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author | Behzad Zeynizadeh Elahe Gholamiyan Masumeh Gilanizadeh |
author_facet | Behzad Zeynizadeh Elahe Gholamiyan Masumeh Gilanizadeh |
author_sort | Behzad Zeynizadeh |
collection | DOAJ |
description | In this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst for green formylation of structurally diverse alcohols to the corresponding formyl esters using formic acid as a solvent (60-70 °C). All reactions were carried out successfully within 1-120 min to afford the products in 76-96 % yields. Reusibility of CuFe2O4 MNPs was examined 5 times without significant loss of its catalytic activity. |
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id | doaj.art-6952f3ed71a846a8b89d210cc14500d8 |
institution | Directory Open Access Journal |
issn | 1927-7296 1927-730X |
language | English |
last_indexed | 2024-12-20T21:12:02Z |
publishDate | 2018-11-01 |
publisher | Growing Science |
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series | Current Chemistry Letters |
spelling | doaj.art-6952f3ed71a846a8b89d210cc14500d82022-12-21T19:26:30ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2018-11-017412113010.5267/j.ccl.2018.11.001Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcoholsBehzad ZeynizadehElahe GholamiyanMasumeh GilanizadehIn this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst for green formylation of structurally diverse alcohols to the corresponding formyl esters using formic acid as a solvent (60-70 °C). All reactions were carried out successfully within 1-120 min to afford the products in 76-96 % yields. Reusibility of CuFe2O4 MNPs was examined 5 times without significant loss of its catalytic activity.http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdfAlcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic |
spellingShingle | Behzad Zeynizadeh Elahe Gholamiyan Masumeh Gilanizadeh Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols Current Chemistry Letters Alcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic |
title | Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
title_full | Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
title_fullStr | Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
title_full_unstemmed | Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
title_short | Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
title_sort | magnetically recoverable cufe2o4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols |
topic | Alcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic |
url | http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdf |
work_keys_str_mv | AT behzadzeynizadeh magneticallyrecoverablecufe2o4nanoparticlesasanefficientheterogeneouscatalystforgreenformylationofalcohols AT elahegholamiyan magneticallyrecoverablecufe2o4nanoparticlesasanefficientheterogeneouscatalystforgreenformylationofalcohols AT masumehgilanizadeh magneticallyrecoverablecufe2o4nanoparticlesasanefficientheterogeneouscatalystforgreenformylationofalcohols |