Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols

In this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst f...

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Main Authors: Behzad Zeynizadeh, Elahe Gholamiyan, Masumeh Gilanizadeh
Format: Article
Language:English
Published: Growing Science 2018-11-01
Series:Current Chemistry Letters
Subjects:
Online Access:http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdf
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author Behzad Zeynizadeh
Elahe Gholamiyan
Masumeh Gilanizadeh
author_facet Behzad Zeynizadeh
Elahe Gholamiyan
Masumeh Gilanizadeh
author_sort Behzad Zeynizadeh
collection DOAJ
description In this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst for green formylation of structurally diverse alcohols to the corresponding formyl esters using formic acid as a solvent (60-70 °C). All reactions were carried out successfully within 1-120 min to afford the products in 76-96 % yields. Reusibility of CuFe2O4 MNPs was examined 5 times without significant loss of its catalytic activity.
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spelling doaj.art-6952f3ed71a846a8b89d210cc14500d82022-12-21T19:26:30ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2018-11-017412113010.5267/j.ccl.2018.11.001Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcoholsBehzad ZeynizadehElahe GholamiyanMasumeh GilanizadehIn this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques. Super paramagnetic CuFe2O4 was used as an efficient catalyst for green formylation of structurally diverse alcohols to the corresponding formyl esters using formic acid as a solvent (60-70 °C). All reactions were carried out successfully within 1-120 min to afford the products in 76-96 % yields. Reusibility of CuFe2O4 MNPs was examined 5 times without significant loss of its catalytic activity.http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdfAlcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic
spellingShingle Behzad Zeynizadeh
Elahe Gholamiyan
Masumeh Gilanizadeh
Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
Current Chemistry Letters
Alcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic
title Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
title_full Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
title_fullStr Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
title_full_unstemmed Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
title_short Magnetically recoverable CuFe2O4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
title_sort magnetically recoverable cufe2o4 nanoparticles as an efficient heterogeneous catalyst for green formylation of alcohols
topic Alcohols CuFe2O4 Formylation Nanoparticles Super paramagnetic
url http://www.growingscience.com/ccl/Vol7/ccl_2018_14.pdf
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AT elahegholamiyan magneticallyrecoverablecufe2o4nanoparticlesasanefficientheterogeneouscatalystforgreenformylationofalcohols
AT masumehgilanizadeh magneticallyrecoverablecufe2o4nanoparticlesasanefficientheterogeneouscatalystforgreenformylationofalcohols