Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de alfa-metileno-gama-butirolactonas Monoterpênicas

Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de alfa-metileno-gama-butirolactonas Monoterpênicas

(R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural a-methylene-g-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control...

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Bibliographic Details
Main Authors: Reginaldo Bezerra dos Santos, Roberta Cecília Vettoraci César, Valdemar Lacerda Jr., Sandro José Greco, Alvaro Cunha Neto
Format: Article
Language:English
Published: Universidade Federal de Mato Grosso do Sul 2015-12-01
Series:Orbital: The Electronic Journal of Chemistry
Subjects:
(R)-(-)-carvone
monoterpene
-methylene--butyrolactones
stereoselective synthesis
Online Access:https://periodicos.ufms.br/index.php/orbital/article/view/17853
Description
Summary:(R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural a-methylene-g-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control of regioselectivity and stereoselectivity. DOI: http://dx.doi.org/10.17807/orbital.v7i4.728
ISSN:1984-6428

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