Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection
Black phosphorus (BP) has emerged as an exciting 2D material for optics, photonics, and electronics. However, there are few studies on BP in terms of modulation and enhancement of their electronic and optical properties and their concurrent reactivity and hence reduction after exposure to the ambien...
| Main Authors: | , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2021-11-01
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| Series: | Advanced Photonics Research |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/adpr.202100150 |
| _version_ | 1818433372564750336 |
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| author | Mei Xian Low Sruthi Kuriakose Qian Liu Patrick D. Taylor Dashen Dong Terry Chien-Jen Yang Taimur Ahmed Gregory Wilson Michelle J. S. Spencer Sherif Abdulkader Tawfik Sharath Sriram Madhu Bhaskaran Prashant Sonar Sumeet Walia |
| author_facet | Mei Xian Low Sruthi Kuriakose Qian Liu Patrick D. Taylor Dashen Dong Terry Chien-Jen Yang Taimur Ahmed Gregory Wilson Michelle J. S. Spencer Sherif Abdulkader Tawfik Sharath Sriram Madhu Bhaskaran Prashant Sonar Sumeet Walia |
| author_sort | Mei Xian Low |
| collection | DOAJ |
| description | Black phosphorus (BP) has emerged as an exciting 2D material for optics, photonics, and electronics. However, there are few studies on BP in terms of modulation and enhancement of their electronic and optical properties and their concurrent reactivity and hence reduction after exposure to the ambient environment. To resolve such challenges, creating inorganic–organic hybrid materials is a suitable approach that offers significant opportunities to enhance the utility of BP by combining them with an organic material which has a complementary set of properties. Herein, a hybrid‐layered BP material coupled with a low bandgap donor–acceptor organic semiconducting polymer, selenophene‐flanked diketopyrrolopyrrole with thienyl‐vinylene‐thienyl (PDPPSe–TVT) is reported, to broaden the optical absorption and tune the ambipolar field effect transistor characteristics. A highly sensitive, nongated broadband photodetection capability of the hybrid device with a detection range from UV–vis to near‐IR (280–1050 nm) and responsivities of up to 4.22 × 103 A W−1 in ambient conditions. In addition to improved photodetection, simultaneous enhancement in both hole (71%) and electron (91%) mobilities is achieved while protecting the sensitive BP material from rapid environmental degradation. The findings therefore report a breakthrough in enhancing the utility of BP as a light‐active material for versatile photonics and electronics applications without operating in an inert environment. |
| first_indexed | 2024-12-14T16:20:03Z |
| format | Article |
| id | doaj.art-6989e2c7fd5b4c3996bbad1404343d2e |
| institution | Directory Open Access Journal |
| issn | 2699-9293 |
| language | English |
| last_indexed | 2024-12-14T16:20:03Z |
| publishDate | 2021-11-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Advanced Photonics Research |
| spelling | doaj.art-6989e2c7fd5b4c3996bbad1404343d2e2022-12-21T22:54:50ZengWiley-VCHAdvanced Photonics Research2699-92932021-11-01211n/an/a10.1002/adpr.202100150Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and PhotodetectionMei Xian Low0Sruthi Kuriakose1Qian Liu2Patrick D. Taylor3Dashen Dong4Terry Chien-Jen Yang5Taimur Ahmed6Gregory Wilson7Michelle J. S. Spencer8Sherif Abdulkader Tawfik9Sharath Sriram10Madhu Bhaskaran11Prashant Sonar12Sumeet Walia13Functional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaCentre for Materials Science Queensland University of Technology (QUT) Brisbane QLD 4000 AustraliaSchool of Science RMIT University GPO Box 2476 Melbourne VIC 3001 AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaCSIRO Solar Technologies Mayfield West NSW 2304 AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaCSIRO Solar Technologies Mayfield West NSW 2304 AustraliaSchool of Science RMIT University GPO Box 2476 Melbourne VIC 3001 AustraliaSchool of Science RMIT University GPO Box 2476 Melbourne VIC 3001 AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaCentre for Materials Science Queensland University of Technology (QUT) Brisbane QLD 4000 AustraliaFunctional Materials and Microsystems Research Group and the Micro Nano Research Facility RMIT University Melbourne AustraliaBlack phosphorus (BP) has emerged as an exciting 2D material for optics, photonics, and electronics. However, there are few studies on BP in terms of modulation and enhancement of their electronic and optical properties and their concurrent reactivity and hence reduction after exposure to the ambient environment. To resolve such challenges, creating inorganic–organic hybrid materials is a suitable approach that offers significant opportunities to enhance the utility of BP by combining them with an organic material which has a complementary set of properties. Herein, a hybrid‐layered BP material coupled with a low bandgap donor–acceptor organic semiconducting polymer, selenophene‐flanked diketopyrrolopyrrole with thienyl‐vinylene‐thienyl (PDPPSe–TVT) is reported, to broaden the optical absorption and tune the ambipolar field effect transistor characteristics. A highly sensitive, nongated broadband photodetection capability of the hybrid device with a detection range from UV–vis to near‐IR (280–1050 nm) and responsivities of up to 4.22 × 103 A W−1 in ambient conditions. In addition to improved photodetection, simultaneous enhancement in both hole (71%) and electron (91%) mobilities is achieved while protecting the sensitive BP material from rapid environmental degradation. The findings therefore report a breakthrough in enhancing the utility of BP as a light‐active material for versatile photonics and electronics applications without operating in an inert environment.https://doi.org/10.1002/adpr.2021001502D materialsambient stabilitiesblack phosphorusorganic–inorganic hybrid materialsphotodetectors |
| spellingShingle | Mei Xian Low Sruthi Kuriakose Qian Liu Patrick D. Taylor Dashen Dong Terry Chien-Jen Yang Taimur Ahmed Gregory Wilson Michelle J. S. Spencer Sherif Abdulkader Tawfik Sharath Sriram Madhu Bhaskaran Prashant Sonar Sumeet Walia Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection Advanced Photonics Research 2D materials ambient stabilities black phosphorus organic–inorganic hybrid materials photodetectors |
| title | Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection |
| title_full | Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection |
| title_fullStr | Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection |
| title_full_unstemmed | Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection |
| title_short | Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection |
| title_sort | black phosphorus diketopyrrolopyrrole polymer semiconductor hybrid for enhanced charge transfer and photodetection |
| topic | 2D materials ambient stabilities black phosphorus organic–inorganic hybrid materials photodetectors |
| url | https://doi.org/10.1002/adpr.202100150 |
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