Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats

Electrically conductive polyaniline (PANI)-coated electrospun poly(vinylidene fluoride) (PVDF) mats were fabricated through aniline (ANI) oxidative polymerization on electrospun PVDF mats. The effect of polymerization condition on structure and property of PVDF/PANI mats was investigated. The electr...

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Main Authors: Claudia eMerlini, Guilherme Mariz De Oliveira Barra, Sílvia Daniela Araújo Da Silva Ramoa, Giseli eContri, Rosemeire dos Santos Almeida, Marcos Akira D´Ávila, Bluma G. Soares
Format: Article
Language:English
Published: Frontiers Media S.A. 2015-02-01
Series:Frontiers in Materials
Subjects:
Online Access:http://journal.frontiersin.org/Journal/10.3389/fmats.2015.00014/full
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author Claudia eMerlini
Guilherme Mariz De Oliveira Barra
Sílvia Daniela Araújo Da Silva Ramoa
Giseli eContri
Rosemeire dos Santos Almeida
Marcos Akira D´Ávila
Bluma G. Soares
author_facet Claudia eMerlini
Guilherme Mariz De Oliveira Barra
Sílvia Daniela Araújo Da Silva Ramoa
Giseli eContri
Rosemeire dos Santos Almeida
Marcos Akira D´Ávila
Bluma G. Soares
author_sort Claudia eMerlini
collection DOAJ
description Electrically conductive polyaniline (PANI)-coated electrospun poly(vinylidene fluoride) (PVDF) mats were fabricated through aniline (ANI) oxidative polymerization on electrospun PVDF mats. The effect of polymerization condition on structure and property of PVDF/PANI mats was investigated. The electrical conductivity and PANI content enhanced significantly with increasing ANI concentration due to the formation of a conducting polymer layer that completely coated the PVDF fibers surface. The PANI deposition on the PVDF fibers surface increased the Young Modulus and the elongation at break reduced significantly. Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) revealed that the electrospun PVDF and PVDF/PANI mats display a polymorph crystalline structure, with absorption bands associated to the β, α and γ phases.
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spelling doaj.art-699df4259f8b4f249a0162e1dd570f812022-12-22T00:28:09ZengFrontiers Media S.A.Frontiers in Materials2296-80162015-02-01210.3389/fmats.2015.00014129145Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) matsClaudia eMerlini0Guilherme Mariz De Oliveira Barra1Sílvia Daniela Araújo Da Silva Ramoa2Giseli eContri3Rosemeire dos Santos Almeida4Marcos Akira D´Ávila5Bluma G. Soares6Federal University of Santa CatarinaFederal University of Santa CatarinaFederal University of Santa CatarinaFederal University of Santa CatarinaUniversidade Estadual de CampinasUniversidade Estadual de CampinasUniversidade Federal do Rio de JaneiroElectrically conductive polyaniline (PANI)-coated electrospun poly(vinylidene fluoride) (PVDF) mats were fabricated through aniline (ANI) oxidative polymerization on electrospun PVDF mats. The effect of polymerization condition on structure and property of PVDF/PANI mats was investigated. The electrical conductivity and PANI content enhanced significantly with increasing ANI concentration due to the formation of a conducting polymer layer that completely coated the PVDF fibers surface. The PANI deposition on the PVDF fibers surface increased the Young Modulus and the elongation at break reduced significantly. Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) revealed that the electrospun PVDF and PVDF/PANI mats display a polymorph crystalline structure, with absorption bands associated to the β, α and γ phases.http://journal.frontiersin.org/Journal/10.3389/fmats.2015.00014/fullConductive membranespolyanilinePoly(vinylidene fluoride)Electrospinnigin situ polymerization.
spellingShingle Claudia eMerlini
Guilherme Mariz De Oliveira Barra
Sílvia Daniela Araújo Da Silva Ramoa
Giseli eContri
Rosemeire dos Santos Almeida
Marcos Akira D´Ávila
Bluma G. Soares
Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
Frontiers in Materials
Conductive membranes
polyaniline
Poly(vinylidene fluoride)
Electrospinnig
in situ polymerization.
title Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
title_full Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
title_fullStr Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
title_full_unstemmed Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
title_short Electrically conductive polyaniline-coated electrospun poly(vinylidene fluoride) mats
title_sort electrically conductive polyaniline coated electrospun poly vinylidene fluoride mats
topic Conductive membranes
polyaniline
Poly(vinylidene fluoride)
Electrospinnig
in situ polymerization.
url http://journal.frontiersin.org/Journal/10.3389/fmats.2015.00014/full
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AT silviadanielaaraujodasilvaramoa electricallyconductivepolyanilinecoatedelectrospunpolyvinylidenefluoridemats
AT giseliecontri electricallyconductivepolyanilinecoatedelectrospunpolyvinylidenefluoridemats
AT rosemeiredossantosalmeida electricallyconductivepolyanilinecoatedelectrospunpolyvinylidenefluoridemats
AT marcosakiradavila electricallyconductivepolyanilinecoatedelectrospunpolyvinylidenefluoridemats
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