Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the sy...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2010-04-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/15/4/2564/ |
| _version_ | 1818157116047753216 |
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| author | Eric G. Morales-Espinoza Karla E. Sanchez-Montes Elena Klimova Tatiana Klimova Irina V. Lijanova José L. Maldonado Gabriel Ramos-Ortíz Simón Hernández-Ortega Marcos Martínez-García |
| author_facet | Eric G. Morales-Espinoza Karla E. Sanchez-Montes Elena Klimova Tatiana Klimova Irina V. Lijanova José L. Maldonado Gabriel Ramos-Ortíz Simón Hernández-Ortega Marcos Martínez-García |
| author_sort | Eric G. Morales-Espinoza |
| collection | DOAJ |
| description | Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by 1H- and 13C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm. |
| first_indexed | 2024-12-11T15:09:04Z |
| format | Article |
| id | doaj.art-699eea33702c48c4b527aa803730ea1f |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-11T15:09:04Z |
| publishDate | 2010-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-699eea33702c48c4b527aa803730ea1f2022-12-22T01:00:48ZengMDPI AGMolecules1420-30492010-04-011542564257510.3390/molecules15042564Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical BehaviorEric G. Morales-EspinozaKarla E. Sanchez-MontesElena KlimovaTatiana KlimovaIrina V. LijanovaJosé L. MaldonadoGabriel Ramos-OrtízSimón Hernández-OrtegaMarcos Martínez-GarcíaDendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by 1H- and 13C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm.http://www.mdpi.com/1420-3049/15/4/2564/ferroceneporphyrindendrimersnon-linear optics |
| spellingShingle | Eric G. Morales-Espinoza Karla E. Sanchez-Montes Elena Klimova Tatiana Klimova Irina V. Lijanova José L. Maldonado Gabriel Ramos-Ortíz Simón Hernández-Ortega Marcos Martínez-García Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior Molecules ferrocene porphyrin dendrimers non-linear optics |
| title | Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior |
| title_full | Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior |
| title_fullStr | Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior |
| title_full_unstemmed | Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior |
| title_short | Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior |
| title_sort | dendrimers containing ferrocene and porphyrin moieties synthesis and cubic non linear optical behavior |
| topic | ferrocene porphyrin dendrimers non-linear optics |
| url | http://www.mdpi.com/1420-3049/15/4/2564/ |
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