Controlling Thermal Expansion Behaviors of Fence-Like Metal-Organic Frameworks by Varying/Mixing Metal Ions

Controlling Thermal Expansion Behaviors of Fence-Like Metal-Organic Frameworks by Varying/Mixing Metal Ions

Solvothermal reactions of 3-(4-pyridyl)-benzoic acid (Hpba) with a series of transition metal ions yielded isostructral metal-organic frameworks [M(pba)2]·2DMA (MCF-52; M = Ni2+, Co2+, Zn2+, Cd2+, or mixed Zn2+/Cd2+; DMA = N,N-dimethylacetamide) possessing two-dimensional fence-like coordination net...

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Bibliographic Details
Main Authors: Hao-Long Zhou, Jie-Peng Zhang, Xiao-Ming Chen
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-07-01
Series:Frontiers in Chemistry
Subjects:
thermal expansion
porous coordination polymers
metal-organic framework
flexibility
pyridyl-carboxylate
structure-property relationship
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00306/full

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