3-(4-Chlorophenylsulfinyl)-2,4,7-trimethyl-1-benzofuran

In the title compound, C17H15ClO2S, the dihedral angle between the mean plane [r.m.s. deviation = 0.020 (2) Å] of the benzofuran ring system and the mean plane [r.m.s. deviation = 0.011 (1) Å] of the 4-chlorophenyl ring is 72.68 (6)...

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Bibliographic Details
Main Authors: Hong Dae Choi, Pil Ja Seo, Uk Lee
Format: Article
Language:English
Published: International Union of Crystallography 2013-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681302117X
Description
Summary:In the title compound, C17H15ClO2S, the dihedral angle between the mean plane [r.m.s. deviation = 0.020 (2) Å] of the benzofuran ring system and the mean plane [r.m.s. deviation = 0.011 (1) Å] of the 4-chlorophenyl ring is 72.68 (6)°. In the crystal, molecules are linked via pairs of C—H...π interactions into inversion dimers. These dimers are further packed by C—H...O hydrogen bonds into supramolecular chains running along the a-axis direction. In addition, the crystal structure also exhibits π–π interactions between the 4-chlorophenyl rings of adjacent molecules [centroid–centroid distance = 4.094 (3) Å, interplanar distance = 3.648 (3) Å and slippage = 1.656 (3) Å].
ISSN:1600-5368