Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate
In the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S at...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813023027 |
| _version_ | 1819291578922958848 |
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| author | Kai-Long Zhong Cheng-Xian Duan |
| author_facet | Kai-Long Zhong Cheng-Xian Duan |
| author_sort | Kai-Long Zhong |
| collection | DOAJ |
| description | In the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent molecule. The dihedral angle between the two chelating N2C2 groups is 85.61 (8)°. The [NiSO4(C10H8N2)2] and propane-1,2-diol units are held together by a pair of symmetry-related intermolecular O—H...O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent molecule is equally disordered over two positions. |
| first_indexed | 2024-12-24T03:40:52Z |
| format | Article |
| id | doaj.art-69b75e6914464b64977bbe04afc3618b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:40:52Z |
| publishDate | 2013-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-69b75e6914464b64977bbe04afc3618b2022-12-21T17:16:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-09-01699m506m50710.1107/S1600536813023027Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvateKai-Long ZhongCheng-Xian DuanIn the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the mid-point of the hydroxyl C—C bond of the propane-1,2-diol solvent molecule. The dihedral angle between the two chelating N2C2 groups is 85.61 (8)°. The [NiSO4(C10H8N2)2] and propane-1,2-diol units are held together by a pair of symmetry-related intermolecular O—H...O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent molecule is equally disordered over two positions.http://scripts.iucr.org/cgi-bin/paper?S1600536813023027 |
| spellingShingle | Kai-Long Zhong Cheng-Xian Duan Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate Acta Crystallographica Section E |
| title | Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate |
| title_full | Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate |
| title_fullStr | Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate |
| title_full_unstemmed | Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate |
| title_short | Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,2-diol monosolvate |
| title_sort | bis 1 10 phenanthroline 954 2n n 8242 sulfato 954 2o o 8242 nickel ii propane 1 2 diol monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813023027 |
| work_keys_str_mv | AT kailongzhong bis110phenanthroline9542nn8242sulfato9542oo8242nickeliipropane12diolmonosolvate AT chengxianduan bis110phenanthroline9542nn8242sulfato9542oo8242nickeliipropane12diolmonosolvate |