Performance of Low-Pressure-Plasma-Processed RuCo Electrocatalysts for Hydrogen Evolution Reaction

RuCo/acid-treated nickel foam (ANF) has been reported to be an excellent electrocatalyst for the hydrogen evolution reaction (HER). In this study, we perform plasma treatment with Ar, Ar/H _2 (95:5), and Ar/O _2 (95:5) as working gases for surface modification to explore the effect on HER performanc...

Full description

Bibliographic Details
Main Authors: Chia-Yun Tseng, Yu-Lun Su, I-Chih Ni, Chih-I Wu, I-Chun Cheng, Jian-Zhang Chen
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:ECS Advances
Online Access:https://doi.org/10.1149/2754-2734/ad10fa
Description
Summary:RuCo/acid-treated nickel foam (ANF) has been reported to be an excellent electrocatalyst for the hydrogen evolution reaction (HER). In this study, we perform plasma treatment with Ar, Ar/H _2 (95:5), and Ar/O _2 (95:5) as working gases for surface modification to explore the effect on HER performance. The developed electrocatalysts are tested in an alkaline solution (1 M KOH); the results show that Ar/H _2 (95:5) plasma treatment significantly improves the electrocatalytic activity of RuCo/ANF, achieving an overpotential of 98 mV at a current density of 10 mA cm ^−2 . Electrochemical impedance spectroscopy and cyclic voltammetry analyses shSow a large reduction in the charge transfer impedance and a significant increase in the electric double-layer capacitance. This study provides a facile strategy to activate RuCo to improve HER performance.
ISSN:2754-2734