Percolation phenomena in the polymer composites with conducting polymer fillers
The electrical properties of polymer nanocomposites based on dielectric polymer matrices of different types and electrically conductive polymer fillers – polyortotoluidine, polyorthoanisidine and polyaniline have been studied. It is shown that the concentration dependence of the specific conductivit...
| المؤلفون الرئيسيون: | , |
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| التنسيق: | مقال |
| اللغة: | English |
| منشور في: |
Vasyl Stefanyk Precarpathian National University
2021-12-01
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| سلاسل: | Фізика і хімія твердого тіла |
| الموضوعات: | |
| الوصول للمادة أونلاين: | https://journals.pnu.edu.ua/index.php/pcss/article/view/5188 |
| الملخص: | The electrical properties of polymer nanocomposites based on dielectric polymer matrices of different types and electrically conductive polymer fillers – polyortotoluidine, polyorthoanisidine and polyaniline have been studied. It is shown that the concentration dependence of the specific conductivity on the content of fillers has a percolation character with a low “percolation threshold”, which depends on the nature of the polymer matrix and polyaminoarene and is 1.7-10.0 vol.%. The calculated critical parameters of electroconductivity are characteristic of the formation of an infinite 3-dimensional cluster of conductivity and indicate a significant influence of the nature of the components and morphology of the material on the charge transfer processes in such systems. |
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| تدمد: | 1729-4428 2309-8589 |