{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate
In the title compound, [Zn(NCS)(C16H18N4)]ClO4, the ZnII atom is five-coordinated by four N atoms of the Schiff base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine in the basal plane, and by the N atom of a thiocyanate ligand at the apical position, forming a distorted squa...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810021628 |
| _version_ | 1819279955758940160 |
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| author | Fu-Ming Wang |
| author_facet | Fu-Ming Wang |
| author_sort | Fu-Ming Wang |
| collection | DOAJ |
| description | In the title compound, [Zn(NCS)(C16H18N4)]ClO4, the ZnII atom is five-coordinated by four N atoms of the Schiff base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine in the basal plane, and by the N atom of a thiocyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff base is 0.015 (3) Å, and the deviation of the Ni atom from that plane is 0.591 (2) Å. Bond lengths are comparable with those observed in similar zinc(II) complexes with Schiff bases. The two methylene C atoms of the ethane-1,2-diamine bridge of the Schiff base ligand are disordered over two sites with occupancies of 0.587 (3) and 0.413 (3). |
| first_indexed | 2024-12-24T00:36:08Z |
| format | Article |
| id | doaj.art-69dd58146bad463ca806cf36bc833ec2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:36:08Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-69dd58146bad463ca806cf36bc833ec22022-12-21T17:24:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m778m77910.1107/S1600536810021628{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorateFu-Ming WangIn the title compound, [Zn(NCS)(C16H18N4)]ClO4, the ZnII atom is five-coordinated by four N atoms of the Schiff base ligand N,N′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine in the basal plane, and by the N atom of a thiocyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff base is 0.015 (3) Å, and the deviation of the Ni atom from that plane is 0.591 (2) Å. Bond lengths are comparable with those observed in similar zinc(II) complexes with Schiff bases. The two methylene C atoms of the ethane-1,2-diamine bridge of the Schiff base ligand are disordered over two sites with occupancies of 0.587 (3) and 0.413 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536810021628 |
| spellingShingle | Fu-Ming Wang {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate Acta Crystallographica Section E |
| title | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate |
| title_full | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate |
| title_fullStr | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate |
| title_full_unstemmed | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate |
| title_short | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate |
| title_sort | n n amp 8242 bis 1 2 pyridyl ethylidene ethane 1 2 diamine amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 thiocyanato amp 954 n zinc ii perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810021628 |
| work_keys_str_mv | AT fumingwang nnamp8242bis12pyridylethylideneethane12diamineamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242thiocyanatoamp954nzinciiperchlorate |