Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions
New solvent systems for selective separation of palladium from nuclear wastes represent a prospective way to reduce the total waste volume and induce this metal’s extraction. For this purpose, the potential of modern green solvent room-temperature ionic liquid was assessed with diamide-type extracta...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-01-01
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| Series: | Metals |
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| Online Access: | https://www.mdpi.com/2075-4701/14/2/133 |
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| author | Alfiya M. Safiulina Nataliya E. Borisova Ekaterina A. Karpyuk Alexey V. Ivanov Dmitry A. Lopatin |
| author_facet | Alfiya M. Safiulina Nataliya E. Borisova Ekaterina A. Karpyuk Alexey V. Ivanov Dmitry A. Lopatin |
| author_sort | Alfiya M. Safiulina |
| collection | DOAJ |
| description | New solvent systems for selective separation of palladium from nuclear wastes represent a prospective way to reduce the total waste volume and induce this metal’s extraction. For this purpose, the potential of modern green solvent room-temperature ionic liquid was assessed with diamide-type extractants based on N-heterocycles and S-donating thiodiglicolic acid. The N-donating heterocyclic extractants demonstrate structure-dependent high selectivity toward palladium in the presence of various impurity metals (such as Zr, Cs, Sr, Mo, Ce, Fe, and Cr) from spent nuclear fuel. Palladium is extracted into the organic phase quite selectively with a separation factor greater than a thousand for all extractants. Ionic liquid media are capable of selective palladium separation from platinum group metals and synergetically increase the selectivity of the extractants. |
| first_indexed | 2024-03-07T22:21:46Z |
| format | Article |
| id | doaj.art-6a12ed481b914c709c6997cf5fd570e6 |
| institution | Directory Open Access Journal |
| issn | 2075-4701 |
| language | English |
| last_indexed | 2024-03-07T22:21:46Z |
| publishDate | 2024-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Metals |
| spelling | doaj.art-6a12ed481b914c709c6997cf5fd570e62024-02-23T15:27:09ZengMDPI AGMetals2075-47012024-01-0114213310.3390/met14020133Extraction of Palladium from Spent Nuclear Fuel Reprocessing SolutionsAlfiya M. Safiulina0Nataliya E. Borisova1Ekaterina A. Karpyuk2Alexey V. Ivanov3Dmitry A. Lopatin4Institute of Materials of Modern Energy and Nanotechnology, D. Mendeleev University of Chemical Technology of Russia, Moscow 125047, RussiaChemistry Department, Moscow State University, Moscow 119991, RussiaChemistry Department, Moscow State University, Moscow 119991, RussiaChemistry Department, Moscow State University, Moscow 119991, RussiaChemistry Department, Moscow State University, Moscow 119991, RussiaNew solvent systems for selective separation of palladium from nuclear wastes represent a prospective way to reduce the total waste volume and induce this metal’s extraction. For this purpose, the potential of modern green solvent room-temperature ionic liquid was assessed with diamide-type extractants based on N-heterocycles and S-donating thiodiglicolic acid. The N-donating heterocyclic extractants demonstrate structure-dependent high selectivity toward palladium in the presence of various impurity metals (such as Zr, Cs, Sr, Mo, Ce, Fe, and Cr) from spent nuclear fuel. Palladium is extracted into the organic phase quite selectively with a separation factor greater than a thousand for all extractants. Ionic liquid media are capable of selective palladium separation from platinum group metals and synergetically increase the selectivity of the extractants.https://www.mdpi.com/2075-4701/14/2/133spent nuclear fuelpalladiumsilverextractionionic liquidsbipyridyl |
| spellingShingle | Alfiya M. Safiulina Nataliya E. Borisova Ekaterina A. Karpyuk Alexey V. Ivanov Dmitry A. Lopatin Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions Metals spent nuclear fuel palladium silver extraction ionic liquids bipyridyl |
| title | Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions |
| title_full | Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions |
| title_fullStr | Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions |
| title_full_unstemmed | Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions |
| title_short | Extraction of Palladium from Spent Nuclear Fuel Reprocessing Solutions |
| title_sort | extraction of palladium from spent nuclear fuel reprocessing solutions |
| topic | spent nuclear fuel palladium silver extraction ionic liquids bipyridyl |
| url | https://www.mdpi.com/2075-4701/14/2/133 |
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