Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis

Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis

A new class of bis-cyclometalated iridium(III) catalysts containing two inert cyclometalated 6-<i>tert</i>-butyl-2-phenyl-2<i>H</i>-indazole bidentate ligands or two inert cyclometalated 5-<i>tert</i>-butyl-1-methyl-2-phenylbenzimidazoles is introduced. The coordi...

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Bibliographic Details
Main Authors: Sebastian Brunen, Yvonne Grell, Philipp S. Steinlandt, Klaus Harms, Eric Meggers
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Molecules
Subjects:
cyclometalation
chiral-at-metal
asymmetric catalysis
Online Access:https://www.mdpi.com/1420-3049/26/7/1822

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