Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)}
In the crystal structure of the title complex, [Cu2(CH3COO)4(C12H11ClN2)2], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of CuII atoms. The coordination of the metal atom is distorted octahedral within a donor set...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030187 |
| _version_ | 1828855993983827968 |
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| author | Zainal A. Fairuz Zaharah Aiyub Zanariah Abdullah Seik Weng Ng Edward R. T. Tiekink |
| author_facet | Zainal A. Fairuz Zaharah Aiyub Zanariah Abdullah Seik Weng Ng Edward R. T. Tiekink |
| author_sort | Zainal A. Fairuz |
| collection | DOAJ |
| description | In the crystal structure of the title complex, [Cu2(CH3COO)4(C12H11ClN2)2], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of CuII atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H...O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H...π type link molecules in the crystal structure. |
| first_indexed | 2024-12-13T01:05:11Z |
| format | Article |
| id | doaj.art-6a25ed305eb349b88d79de66b2d3861a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:05:11Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6a25ed305eb349b88d79de66b2d3861a2022-12-22T00:04:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1049m105010.1107/S1600536810030187Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)}Zainal A. FairuzZaharah AiyubZanariah AbdullahSeik Weng NgEdward R. T. TiekinkIn the crystal structure of the title complex, [Cu2(CH3COO)4(C12H11ClN2)2], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of CuII atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H...O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H...π type link molecules in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810030187 |
| spellingShingle | Zainal A. Fairuz Zaharah Aiyub Zanariah Abdullah Seik Weng Ng Edward R. T. Tiekink Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} Acta Crystallographica Section E |
| title | Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} |
| title_full | Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} |
| title_fullStr | Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} |
| title_full_unstemmed | Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} |
| title_short | Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)} |
| title_sort | tetra amp 956 acetato amp 954 8o o amp 8242 bis n 4 chlorophenyl 4 methylpyridin 2 amine amp 954 n1 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810030187 |
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