Methanol Reforming Processes for Fuel Cell Applications

Hydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol has attracted great interest as reformate gas strea...

Full description

Bibliographic Details
Main Authors: Konstantinos Kappis, Joan Papavasiliou, George Avgouropoulos
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/24/8442
_version_ 1797505046383951872
author Konstantinos Kappis
Joan Papavasiliou
George Avgouropoulos
author_facet Konstantinos Kappis
Joan Papavasiliou
George Avgouropoulos
author_sort Konstantinos Kappis
collection DOAJ
description Hydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol has attracted great interest as reformate gas stream where high concentration of hydrogen is produced with a negligible amount of carbon monoxide. In this review, recent progress of the main reforming processes of methanol towards hydrogen production is summarized. Different catalytic systems are reviewed for the steam reforming of methanol: mainly copper- and group 8–10-based catalysts, highlighting the catalytic key properties, while the promoting effect of the latter group in copper activity and selectivity is also discussed. The effect of different preparation methods, different promoters/stabilizers, and the formation mechanism is analyzed. Moreover, the integration of methanol steam reforming process and the high temperature–polymer electrolyte membrane fuel cells (HT-PEMFCs) for the development of clean energy production is discussed.
first_indexed 2024-03-10T04:13:05Z
format Article
id doaj.art-6aa48a4c139148ee9629575f8e9ccb8d
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-03-10T04:13:05Z
publishDate 2021-12-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-6aa48a4c139148ee9629575f8e9ccb8d2023-11-23T08:07:19ZengMDPI AGEnergies1996-10732021-12-011424844210.3390/en14248442Methanol Reforming Processes for Fuel Cell ApplicationsKonstantinos Kappis0Joan Papavasiliou1George Avgouropoulos2Department of Materials Science, University of Patras, GR-26504 Patras, GreeceDepartment of Materials Science, University of Patras, GR-26504 Patras, GreeceDepartment of Materials Science, University of Patras, GR-26504 Patras, GreeceHydrogen production through methanol reforming processes has been stimulated over the years due to increasing interest in fuel cell technology and clean energy production. Among different types of methanol reforming, the steam reforming of methanol has attracted great interest as reformate gas stream where high concentration of hydrogen is produced with a negligible amount of carbon monoxide. In this review, recent progress of the main reforming processes of methanol towards hydrogen production is summarized. Different catalytic systems are reviewed for the steam reforming of methanol: mainly copper- and group 8–10-based catalysts, highlighting the catalytic key properties, while the promoting effect of the latter group in copper activity and selectivity is also discussed. The effect of different preparation methods, different promoters/stabilizers, and the formation mechanism is analyzed. Moreover, the integration of methanol steam reforming process and the high temperature–polymer electrolyte membrane fuel cells (HT-PEMFCs) for the development of clean energy production is discussed.https://www.mdpi.com/1996-1073/14/24/8442steam reforming of methanolcopper catalystshydrogen productionfuel cellsHT-PEMFCs
spellingShingle Konstantinos Kappis
Joan Papavasiliou
George Avgouropoulos
Methanol Reforming Processes for Fuel Cell Applications
Energies
steam reforming of methanol
copper catalysts
hydrogen production
fuel cells
HT-PEMFCs
title Methanol Reforming Processes for Fuel Cell Applications
title_full Methanol Reforming Processes for Fuel Cell Applications
title_fullStr Methanol Reforming Processes for Fuel Cell Applications
title_full_unstemmed Methanol Reforming Processes for Fuel Cell Applications
title_short Methanol Reforming Processes for Fuel Cell Applications
title_sort methanol reforming processes for fuel cell applications
topic steam reforming of methanol
copper catalysts
hydrogen production
fuel cells
HT-PEMFCs
url https://www.mdpi.com/1996-1073/14/24/8442
work_keys_str_mv AT konstantinoskappis methanolreformingprocessesforfuelcellapplications
AT joanpapavasiliou methanolreformingprocessesforfuelcellapplications
AT georgeavgouropoulos methanolreformingprocessesforfuelcellapplications