Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode
A polypyrrole/chitosan composite material was obtained by chemical polymerization. The adsorption performance of a hot-molded polypyrrole/chitosan composite electrode was tested by adsorption/desorption experiments. Scanning electron microscopy and Fourier-transform infrared spectroscopy both showed...
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Format: | Article |
Language: | English |
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SAGE Publications
2019-05-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1177/0263617418822225 |
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author | Yujie Zhang Quanqin Xue Fei Li Jizhe Dai |
author_facet | Yujie Zhang Quanqin Xue Fei Li Jizhe Dai |
author_sort | Yujie Zhang |
collection | DOAJ |
description | A polypyrrole/chitosan composite material was obtained by chemical polymerization. The adsorption performance of a hot-molded polypyrrole/chitosan composite electrode was tested by adsorption/desorption experiments. Scanning electron microscopy and Fourier-transform infrared spectroscopy both showed the deposition of polypyrrole on the chitosan surface. The specific capacitance of the polypyrrole/chitosan composite was determined by cyclic voltammetry in 1.0 M KCl at 0.01 V/s as 102.96 F/g. The adsorption/desorption experiments indicated that the specific adsorption capacity of the composite for Cu 2+ was 99.67 mg/g, while the removal performance for other metal ions, such as Ag + , Pb 2+ , and Cd 2+ , was good. The results of multicycle adsorption/desorption tests showed that the adsorption rate of the polypyrrole/chitosan composite electrode for Cu 2+ was decreased from 56.4 to 51.4% over 10 cycles, demonstrating the stable metal-ion adsorption/desorption behavior of the composite electrode. The obtained performances show that the prepared polypyrrole/chitosan composite material is an ideal electrode material for the removal of heavy metal ions. |
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issn | 0263-6174 2048-4038 |
language | English |
last_indexed | 2024-03-07T17:35:02Z |
publishDate | 2019-05-01 |
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series | Adsorption Science & Technology |
spelling | doaj.art-6ae1029391804b61b0e258112dc3ef512024-03-02T17:10:12ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382019-05-013710.1177/0263617418822225Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrodeYujie ZhangQuanqin XueFei LiJizhe DaiA polypyrrole/chitosan composite material was obtained by chemical polymerization. The adsorption performance of a hot-molded polypyrrole/chitosan composite electrode was tested by adsorption/desorption experiments. Scanning electron microscopy and Fourier-transform infrared spectroscopy both showed the deposition of polypyrrole on the chitosan surface. The specific capacitance of the polypyrrole/chitosan composite was determined by cyclic voltammetry in 1.0 M KCl at 0.01 V/s as 102.96 F/g. The adsorption/desorption experiments indicated that the specific adsorption capacity of the composite for Cu 2+ was 99.67 mg/g, while the removal performance for other metal ions, such as Ag + , Pb 2+ , and Cd 2+ , was good. The results of multicycle adsorption/desorption tests showed that the adsorption rate of the polypyrrole/chitosan composite electrode for Cu 2+ was decreased from 56.4 to 51.4% over 10 cycles, demonstrating the stable metal-ion adsorption/desorption behavior of the composite electrode. The obtained performances show that the prepared polypyrrole/chitosan composite material is an ideal electrode material for the removal of heavy metal ions.https://doi.org/10.1177/0263617418822225 |
spellingShingle | Yujie Zhang Quanqin Xue Fei Li Jizhe Dai Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode Adsorption Science & Technology |
title | Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode |
title_full | Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode |
title_fullStr | Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode |
title_full_unstemmed | Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode |
title_short | Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode |
title_sort | removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole chitosan composite electrode |
url | https://doi.org/10.1177/0263617418822225 |
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