Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil
Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydro...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2018-04-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/1508 |
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| author | Yustia Wulandari Mirzayanti Firman Kurniawansyah Danawati Hari Prayitno Achmad Roesyadi |
| author_facet | Yustia Wulandari Mirzayanti Firman Kurniawansyah Danawati Hari Prayitno Achmad Roesyadi |
| author_sort | Yustia Wulandari Mirzayanti |
| collection | DOAJ |
| description | Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400 oC for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400 oC. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel. |
| first_indexed | 2024-03-11T22:50:43Z |
| format | Article |
| id | doaj.art-6b15d02b54d64a279e0cdeed0096d7c8 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:43Z |
| publishDate | 2018-04-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-6b15d02b54d64a279e0cdeed0096d7c82023-09-22T03:45:14ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932018-04-0113113614310.9767/bcrec.13.1.1508.136-143913Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oilYustia Wulandari Mirzayanti0Firman Kurniawansyah1Danawati Hari Prayitno2Achmad Roesyadi3Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Sukolilo, Surabaya, 60111, IndonesiaChemical Reaction Engineering Laboratory, Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Sukolilo, Surabaya, 60111, IndonesiaChemical Reaction Engineering Laboratory, Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Sukolilo, Surabaya, 60111, IndonesiaChemical Reaction Engineering Laboratory, Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Sukolilo, Surabaya, 60111, IndonesiaBiofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400 oC for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400 oC. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel.https://journal.bcrec.id/index.php/bcrec/article/view/1508catalytic hydrocrackingceiba pentandra oilzincmo/hzsm-5 catalystliquid hydrocarbon |
| spellingShingle | Yustia Wulandari Mirzayanti Firman Kurniawansyah Danawati Hari Prayitno Achmad Roesyadi Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil Bulletin of Chemical Reaction Engineering & Catalysis catalytic hydrocracking ceiba pentandra oil zincmo/hzsm-5 catalyst liquid hydrocarbon |
| title | Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil |
| title_full | Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil |
| title_fullStr | Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil |
| title_full_unstemmed | Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil |
| title_short | Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil |
| title_sort | zn mo hzsm 5 catalyst for gasoil range hydrocarbon production by catalytic hydrocracking of ceiba pentandra oil |
| topic | catalytic hydrocracking ceiba pentandra oil zincmo/hzsm-5 catalyst liquid hydrocarbon |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/1508 |
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