Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol est...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2009-04-01
|
| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.5.11 |
| _version_ | 1818603256114315264 |
|---|---|
| author | Jiří Kulhánek Filip Bureš Miroslav Ludwig |
| author_facet | Jiří Kulhánek Filip Bureš Miroslav Ludwig |
| author_sort | Jiří Kulhánek |
| collection | DOAJ |
| description | Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions. |
| first_indexed | 2024-12-16T13:20:17Z |
| format | Article |
| id | doaj.art-6b6b1a17028744eea0f7815e8f97dcb6 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-16T13:20:17Z |
| publishDate | 2009-04-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-6b6b1a17028744eea0f7815e8f97dcb62022-12-21T22:30:21ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972009-04-01511110.3762/bjoc.5.111860-5397-5-11Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistryJiří Kulhánek0Filip Bureš1Miroslav Ludwig2Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicInstitute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicInstitute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Čs. legií 565, Pardubice, 532 10, Czech RepublicSimple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.https://doi.org/10.3762/bjoc.5.11boronic aciddonor/acceptorlinkerSonogashira reactionproperty tuningpush-pullSuzuki–Miyaura reaction |
| spellingShingle | Jiří Kulhánek Filip Bureš Miroslav Ludwig Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry Beilstein Journal of Organic Chemistry boronic acid donor/acceptor linker Sonogashira reaction property tuning push-pull Suzuki–Miyaura reaction |
| title | Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry |
| title_full | Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry |
| title_fullStr | Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry |
| title_full_unstemmed | Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry |
| title_short | Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry |
| title_sort | convenient methods for preparing π conjugated linkers as building blocks for modular chemistry |
| topic | boronic acid donor/acceptor linker Sonogashira reaction property tuning push-pull Suzuki–Miyaura reaction |
| url | https://doi.org/10.3762/bjoc.5.11 |
| work_keys_str_mv | AT jirikulhanek convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry AT filipbures convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry AT miroslavludwig convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry |