Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model
A novel, simple numerical method to determine the pore and surface diffusivities in adsorbents from a single experimental concentration decay curve obtained using the batch adsorption technique was investigated in this study. The pore and surface diffusion coefficients were determined based on the c...
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| Format: | Article |
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MDPI AG
2022-11-01
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| Series: | Water |
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| Online Access: | https://www.mdpi.com/2073-4441/14/22/3629 |
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| author | Yoshimi Seida Noriyoshi Sonetaka Kenneth E. Noll Eiji Furuya |
| author_facet | Yoshimi Seida Noriyoshi Sonetaka Kenneth E. Noll Eiji Furuya |
| author_sort | Yoshimi Seida |
| collection | DOAJ |
| description | A novel, simple numerical method to determine the pore and surface diffusivities in adsorbents from a single experimental concentration decay curve obtained using the batch adsorption technique was investigated in this study. The pore and surface diffusion coefficients were determined based on the conventional parallel diffusion model in its dimensionless form using a theoretical model correlation. The model assumed that the film mass transfer resistance was negligible, i.e., the condition with a large Biot number, from the single concentration decay curve. The procedure for determining the kinetic parameters was investigated, and the effectiveness of the proposed simple method was validated by comparing the parameters with those reported previously. The single decay curve of <i>p</i>-nitrophenol, obtained by the batch adsorption system using granular activated carbon as an adsorbent, was used for validation. The diffusivities determined by the simple method corresponded fairly well with the diffusivities reported previously. |
| first_indexed | 2024-03-09T17:56:13Z |
| format | Article |
| id | doaj.art-6bbd55c88e9a4e39a5217efa731bb485 |
| institution | Directory Open Access Journal |
| issn | 2073-4441 |
| language | English |
| last_indexed | 2024-03-09T17:56:13Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Water |
| spelling | doaj.art-6bbd55c88e9a4e39a5217efa731bb4852023-11-24T10:20:22ZengMDPI AGWater2073-44412022-11-011422362910.3390/w14223629Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion ModelYoshimi Seida0Noriyoshi Sonetaka1Kenneth E. Noll2Eiji Furuya3Natural Science Laboratory, Toyo University, Bunkyo-ku, Tokyo 112-8606, JapanTechnoMediaLab, Inc., Minato-ku, Tokyo 108-0075, JapanDepartment of Civil, Architectural and Environmental Engineering, Illinois Institute of Technology, Chicago, IL 60616, USADepartment of Applied Chemistry, Meiji University, Kawasaki 214-8571, JapanA novel, simple numerical method to determine the pore and surface diffusivities in adsorbents from a single experimental concentration decay curve obtained using the batch adsorption technique was investigated in this study. The pore and surface diffusion coefficients were determined based on the conventional parallel diffusion model in its dimensionless form using a theoretical model correlation. The model assumed that the film mass transfer resistance was negligible, i.e., the condition with a large Biot number, from the single concentration decay curve. The procedure for determining the kinetic parameters was investigated, and the effectiveness of the proposed simple method was validated by comparing the parameters with those reported previously. The single decay curve of <i>p</i>-nitrophenol, obtained by the batch adsorption system using granular activated carbon as an adsorbent, was used for validation. The diffusivities determined by the simple method corresponded fairly well with the diffusivities reported previously.https://www.mdpi.com/2073-4441/14/22/3629adsorptiondiffusionparallel diffusion modelcompletely mixed batch reactor |
| spellingShingle | Yoshimi Seida Noriyoshi Sonetaka Kenneth E. Noll Eiji Furuya Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model Water adsorption diffusion parallel diffusion model completely mixed batch reactor |
| title | Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model |
| title_full | Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model |
| title_fullStr | Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model |
| title_full_unstemmed | Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model |
| title_short | Determination of Pore and Surface Diffusivities from Single Decay Curve in CSBR Based on Parallel Diffusion Model |
| title_sort | determination of pore and surface diffusivities from single decay curve in csbr based on parallel diffusion model |
| topic | adsorption diffusion parallel diffusion model completely mixed batch reactor |
| url | https://www.mdpi.com/2073-4441/14/22/3629 |
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