Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety
New type of aromatic polyamide/montmorillonite nanocomposites were produced using solution process in N-methyl-2-pyrolidone. Amide chains were synthesized from 4,4′-diaminodiphenyl sulfone and p-phenylenediacrylic acid in N-methyl-2-pyrolidone. The resulting nanocomposite films containing 5–15 mass...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2011-06-01
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| Series: | High Temperature Materials and Processes |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/htmp.2011.034 |
| _version_ | 1818598202804273152 |
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| author | Faghihi Khalil Soleimani Masoumeh Shabanian Meisam Abootalebi Ashraf Sadat |
| author_facet | Faghihi Khalil Soleimani Masoumeh Shabanian Meisam Abootalebi Ashraf Sadat |
| author_sort | Faghihi Khalil |
| collection | DOAJ |
| description | New type of aromatic polyamide/montmorillonite nanocomposites were produced using solution process in N-methyl-2-pyrolidone. Amide chains were synthesized from 4,4′-diaminodiphenyl sulfone and p-phenylenediacrylic acid in N-methyl-2-pyrolidone. The resulting nanocomposite films containing 5–15 mass % of organoclay were characterized for FT-IR, scanning electronmicroscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), optical transparency and water absorption measurements. The distribution of organoclay and nanostructure of the composites were investigated by (XRD) and SEM analyses. Thermogravimetric analysis indicated an increase in thermal stability of nanocomposites as compared to pristine polyamide. The percentage optical transparency and water absorption of these hybrids was found to be much reduced upon the addition of modified layered silicate indicating decreased permeability. |
| first_indexed | 2024-12-16T11:59:57Z |
| format | Article |
| id | doaj.art-6bd5881f8d9e4277ad5db6b258662e79 |
| institution | Directory Open Access Journal |
| issn | 0334-6455 2191-0324 |
| language | English |
| last_indexed | 2024-12-16T11:59:57Z |
| publishDate | 2011-06-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | High Temperature Materials and Processes |
| spelling | doaj.art-6bd5881f8d9e4277ad5db6b258662e792022-12-21T22:32:28ZengDe GruyterHigh Temperature Materials and Processes0334-64552191-03242011-06-0130322322810.1515/htmp.2011.034Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic MoietyFaghihi Khalil0Soleimani Masoumeh1Shabanian Meisam2Abootalebi Ashraf Sadat3Polymer Research Laboratory, Department of Chemistry, Faculty of Science, Islamic Azad University, Arak Branch, Arak, IranIslamic Azad University, Arak Branch, Young Researchers Club, Arak, IranDepatment of Chemistry, Farahan Branch, Islamic Azad University, Farahan, IranIslamic Azad University, Arak Branch, Young Researchers Club, Arak, IranNew type of aromatic polyamide/montmorillonite nanocomposites were produced using solution process in N-methyl-2-pyrolidone. Amide chains were synthesized from 4,4′-diaminodiphenyl sulfone and p-phenylenediacrylic acid in N-methyl-2-pyrolidone. The resulting nanocomposite films containing 5–15 mass % of organoclay were characterized for FT-IR, scanning electronmicroscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), optical transparency and water absorption measurements. The distribution of organoclay and nanostructure of the composites were investigated by (XRD) and SEM analyses. Thermogravimetric analysis indicated an increase in thermal stability of nanocomposites as compared to pristine polyamide. The percentage optical transparency and water absorption of these hybrids was found to be much reduced upon the addition of modified layered silicate indicating decreased permeability.https://doi.org/10.1515/htmp.2011.034nanocompositethermal propertiesorganoclaysolution intercalation |
| spellingShingle | Faghihi Khalil Soleimani Masoumeh Shabanian Meisam Abootalebi Ashraf Sadat Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety High Temperature Materials and Processes nanocomposite thermal properties organoclay solution intercalation |
| title | Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety |
| title_full | Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety |
| title_fullStr | Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety |
| title_full_unstemmed | Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety |
| title_short | Synthesis and Thermal and Photo Behaviors of New Polyamide/Organocaly Nanocomposites Containing Para Phenylenediacrylic Moiety |
| title_sort | synthesis and thermal and photo behaviors of new polyamide organocaly nanocomposites containing para phenylenediacrylic moiety |
| topic | nanocomposite thermal properties organoclay solution intercalation |
| url | https://doi.org/10.1515/htmp.2011.034 |
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