trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
In the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances betwee...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811051658 |
| _version_ | 1819290802259492864 |
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| author | Necmi Dege Güneş Demirtaş Hasan Içbudak |
| author_facet | Necmi Dege Güneş Demirtaş Hasan Içbudak |
| author_sort | Necmi Dege |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances between the CuII ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H...O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H...O hydrogen bonds into chains running along the a axis. |
| first_indexed | 2024-12-24T03:28:32Z |
| format | Article |
| id | doaj.art-6be9e01ee0104f1b9d8cf6b1ead43ab2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:28:32Z |
| publishDate | 2012-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6be9e01ee0104f1b9d8cf6b1ead43ab22022-12-21T17:17:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m47m4810.1107/S1600536811051658trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)Necmi DegeGüneş DemirtaşHasan IçbudakIn the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances between the CuII ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H...O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H...O hydrogen bonds into chains running along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811051658 |
| spellingShingle | Necmi Dege Güneş Demirtaş Hasan Içbudak trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) Acta Crystallographica Section E |
| title | trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) |
| title_full | trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) |
| title_fullStr | trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) |
| title_full_unstemmed | trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) |
| title_short | trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II) |
| title_sort | trans bis ethylenediamine amp 954 2n n amp 8242 bis 6 methyl 2 2 4 trioxo 3 4 dihydro 1 2 amp 955 6 3 oxathiazin 3 ido amp 954 n copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811051658 |
| work_keys_str_mv | AT necmidege transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii AT gamp252neamp351demirtaamp351 transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii AT hasaniamp231budak transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii |