| Summary: | In this study, a highly conductive composite bipolar plate with an embedded conductive carbon nanofiber network was prepared by chemical vapor deposition, and a conductive network was constructed inside the composite bipolar plate. The latter network was then compared with a conductive network formed by directly adding carbon nanotubes more evenly distributed. The optimum preparation methods of vapor-grown carbon fibers and the fiber content were analyzed, and the specific surface area and porosity of the bipolar plates were measured and analyzed using a BET test. The results show that the carbon nanofibers prepared under the conditions of 700 °C and a content of 2% exhibited the best effect on improving the performance of the bipolar plates. The conductivity of the prepared bipolar plates could reach 255.2 S/cm, which is 22.1% higher than treatment with multi-walled carbon nanotubes. The bending strength of the prepared bipolar plates was 47.92 MPa, and the interface contact resistance was 6.24 mΩ·cm<sup>2</sup>. In conclusion, the bipolar plates modified with vapor-grown carbon fibers were a promising kind of material for proton exchange membrane fuel cells.
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