Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy

Magnetic order at room temperature induced by atomic lattice defects, like vacancies, interstitials, or their pairs, has been observed in a large number of different non-magnetic hosts, such as pure graphite, oxides, and silicon-based materials. High Curie temperatures and time-independent magnetic...

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Main Authors: Markus Stiller, Pablo D. Esquinazi
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-02-01
Series:Frontiers in Physics
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fphy.2023.1124924/full
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author Markus Stiller
Pablo D. Esquinazi
author_facet Markus Stiller
Pablo D. Esquinazi
author_sort Markus Stiller
collection DOAJ
description Magnetic order at room temperature induced by atomic lattice defects, like vacancies, interstitials, or their pairs, has been observed in a large number of different non-magnetic hosts, such as pure graphite, oxides, and silicon-based materials. High Curie temperatures and time-independent magnetic response at room temperature indicate the extraordinary robustness of this new phenomenon in solid-state magnetism. In this work, we review experimental and theoretical results of pure TiO2 (anatase), whose magnetic order can be triggered by low-energy ion irradiation. In particular, we discuss the systematic observation of an ultrathin magnetic layer with perpendicular magnetic anisotropy at the surface of this oxide.
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spelling doaj.art-6bfc1f3c8457422d97d7011d3d44d50b2023-02-01T06:22:59ZengFrontiers Media S.A.Frontiers in Physics2296-424X2023-02-011110.3389/fphy.2023.11249241124924Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropyMarkus StillerPablo D. EsquinaziMagnetic order at room temperature induced by atomic lattice defects, like vacancies, interstitials, or their pairs, has been observed in a large number of different non-magnetic hosts, such as pure graphite, oxides, and silicon-based materials. High Curie temperatures and time-independent magnetic response at room temperature indicate the extraordinary robustness of this new phenomenon in solid-state magnetism. In this work, we review experimental and theoretical results of pure TiO2 (anatase), whose magnetic order can be triggered by low-energy ion irradiation. In particular, we discuss the systematic observation of an ultrathin magnetic layer with perpendicular magnetic anisotropy at the surface of this oxide.https://www.frontiersin.org/articles/10.3389/fphy.2023.1124924/fulloxide2D magnetic orderdefect-induced magnetismion irradiationvacancy–interstitial pairssurface ferromagnetism
spellingShingle Markus Stiller
Pablo D. Esquinazi
Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
Frontiers in Physics
oxide
2D magnetic order
defect-induced magnetism
ion irradiation
vacancy–interstitial pairs
surface ferromagnetism
title Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
title_full Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
title_fullStr Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
title_full_unstemmed Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
title_short Defect-induced magnetism in TiO2: An example of quasi 2D magnetic order with perpendicular anisotropy
title_sort defect induced magnetism in tio2 an example of quasi 2d magnetic order with perpendicular anisotropy
topic oxide
2D magnetic order
defect-induced magnetism
ion irradiation
vacancy–interstitial pairs
surface ferromagnetism
url https://www.frontiersin.org/articles/10.3389/fphy.2023.1124924/full
work_keys_str_mv AT markusstiller defectinducedmagnetismintio2anexampleofquasi2dmagneticorderwithperpendicularanisotropy
AT pablodesquinazi defectinducedmagnetismintio2anexampleofquasi2dmagneticorderwithperpendicularanisotropy