Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties
Semiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For α,β-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2000-03-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/5/3/451/ |
| _version_ | 1818018995282903040 |
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| author | S. C. Pellegrinet M. T. Baumgartner R. A. Spanevello |
| author_facet | S. C. Pellegrinet M. T. Baumgartner R. A. Spanevello |
| author_sort | S. C. Pellegrinet |
| collection | DOAJ |
| description | Semiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For α,β-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed. |
| first_indexed | 2024-04-14T07:47:10Z |
| format | Article |
| id | doaj.art-6bfd5d8b3d7f40dabfcfaff100021d04 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-14T07:47:10Z |
| publishDate | 2000-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-6bfd5d8b3d7f40dabfcfaff100021d042022-12-22T02:05:18ZengMDPI AGMolecules1420-30492000-03-015345145210.3390/50300451Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic PropertiesS. C. PellegrinetM. T. BaumgartnerR. A. SpanevelloSemiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For α,β-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed.http://www.mdpi.com/1420-3049/5/3/451/n/a |
| spellingShingle | S. C. Pellegrinet M. T. Baumgartner R. A. Spanevello Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties Molecules n/a |
| title | Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties |
| title_full | Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties |
| title_fullStr | Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties |
| title_full_unstemmed | Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties |
| title_short | Reactivity Comparison of D–Glucose–Derived Dienophiles. Analysis of the Conformational and Electronic Properties |
| title_sort | reactivity comparison of da¢a€a glucosea¢a€a derived dienophiles analysis of the conformational and electronic properties |
| topic | n/a |
| url | http://www.mdpi.com/1420-3049/5/3/451/ |
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