Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness

in this paper show Mix ligand composed of (HL1) Dimidone and (HL2) 1,2-dibenzothiophene were allowed to react with next metal ions: Cobalt (III), Manganese (II), iron (III), Cobalt (II), Nickle (II), Cupper (II), Zinc (II) and Cadmium (II) individually forming stable metal complexes with different g...

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Main Authors: marwa aldulaimi, Omar Shihab
Format: Article
Language:English
Published: University of Anbar 2023-12-01
Series:مجلة جامعة الانبار للعلوم الصرفة
Subjects:
Online Access:https://juaps.uoanbar.edu.iq/article_181558_2490174f8322640605a0271275ece1f1.pdf
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author marwa aldulaimi
Omar Shihab
author_facet marwa aldulaimi
Omar Shihab
author_sort marwa aldulaimi
collection DOAJ
description in this paper show Mix ligand composed of (HL1) Dimidone and (HL2) 1,2-dibenzothiophene were allowed to react with next metal ions: Cobalt (III), Manganese (II), iron (III), Cobalt (II), Nickle (II), Cupper (II), Zinc (II) and Cadmium (II) individually forming stable metal complexes with different geometries as indicated using various techniques. The formation of the complexes as well as the geometries of the complexes were detected by Fourier-transform-infrared, mass_spectra, elemental analysis and electronic spectra. Moreover, the solubility of the compounds was tested in various solvents including: CHCl3, THF, DMF, DMSO, C2H5OH and H2O. Furthermore, the vital effectiveness was tested toward two types of bacteria gram negative bacteria (Spuedomonas & Escherichia coli was abbreviate (E. Coli) and positive bacteria ( Staphylococcus aureus was abbreviate Staph. Aureas & Bacillus) and two types another of fungi (Aspergillus niger & Fuzaium) giving different inhibition values (either effective or noneffective) as detailed in the manuscript.
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spelling doaj.art-6c044d9656a14f7a8f812cc012e4d1e82023-12-28T22:02:45ZengUniversity of Anbarمجلة جامعة الانبار للعلوم الصرفة1991-89412706-67032023-12-0117214415310.37652/juaps.2023.142224.1107181558Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectivenessmarwa aldulaimi0Omar Shihab1Department of Chemistry, College of Science, University of Anbar, Ramadi, Iraq;Department of Chemistry, College of Science, University of Anbar, Ramadi, Iraq;in this paper show Mix ligand composed of (HL1) Dimidone and (HL2) 1,2-dibenzothiophene were allowed to react with next metal ions: Cobalt (III), Manganese (II), iron (III), Cobalt (II), Nickle (II), Cupper (II), Zinc (II) and Cadmium (II) individually forming stable metal complexes with different geometries as indicated using various techniques. The formation of the complexes as well as the geometries of the complexes were detected by Fourier-transform-infrared, mass_spectra, elemental analysis and electronic spectra. Moreover, the solubility of the compounds was tested in various solvents including: CHCl3, THF, DMF, DMSO, C2H5OH and H2O. Furthermore, the vital effectiveness was tested toward two types of bacteria gram negative bacteria (Spuedomonas & Escherichia coli was abbreviate (E. Coli) and positive bacteria ( Staphylococcus aureus was abbreviate Staph. Aureas & Bacillus) and two types another of fungi (Aspergillus niger & Fuzaium) giving different inhibition values (either effective or noneffective) as detailed in the manuscript.https://juaps.uoanbar.edu.iq/article_181558_2490174f8322640605a0271275ece1f1.pdfbiological effectiveness,,,،ft-ir,,,،mixed ligand,,,،mixed ligand.,,,،2-dibenzothiophene
spellingShingle marwa aldulaimi
Omar Shihab
Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
مجلة جامعة الانبار للعلوم الصرفة
biological effectiveness,,
,،ft-ir,,
,،mixed ligand,,
,،mixed ligand.,,
,،2-dibenzothiophene
title Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
title_full Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
title_fullStr Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
title_full_unstemmed Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
title_short Synthesis, Spectroscopic Identification for Mixed-Ligand Complexes and Evaluating Their Biological Effectiveness
title_sort synthesis spectroscopic identification for mixed ligand complexes and evaluating their biological effectiveness
topic biological effectiveness,,
,،ft-ir,,
,،mixed ligand,,
,،mixed ligand.,,
,،2-dibenzothiophene
url https://juaps.uoanbar.edu.iq/article_181558_2490174f8322640605a0271275ece1f1.pdf
work_keys_str_mv AT marwaaldulaimi synthesisspectroscopicidentificationformixedligandcomplexesandevaluatingtheirbiologicaleffectiveness
AT omarshihab synthesisspectroscopicidentificationformixedligandcomplexesandevaluatingtheirbiologicaleffectiveness