Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosp...
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| Format: | Article |
| Language: | English |
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MDPI AG
2016-08-01
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| Series: | Inorganics |
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| Online Access: | http://www.mdpi.com/2304-6740/4/3/26 |
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| author | Christine A. Bange Neil T. Mucha Morgan E. Cousins Abigail C. Gehsmann Anna Singer Taylor Truax Lee J. Higham Rory Waterman |
| author_facet | Christine A. Bange Neil T. Mucha Morgan E. Cousins Abigail C. Gehsmann Anna Singer Taylor Truax Lee J. Higham Rory Waterman |
| author_sort | Christine A. Bange |
| collection | DOAJ |
| description | Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated. |
| first_indexed | 2024-12-18T23:13:22Z |
| format | Article |
| id | doaj.art-6c0d6bd34a5846169417babd1c3d82f6 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-12-18T23:13:22Z |
| publishDate | 2016-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-6c0d6bd34a5846169417babd1c3d82f62022-12-21T20:48:17ZengMDPI AGInorganics2304-67402016-08-01432610.3390/inorganics4030026inorganics4030026Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary PhosphineChristine A. Bange0Neil T. Mucha1Morgan E. Cousins2Abigail C. Gehsmann3Anna Singer4Taylor Truax5Lee J. Higham6Rory Waterman7Department of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USADepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USADepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USADepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USADepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USADepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USASchool of Chemistry, Newcastle University, Newcastle upon Tyne NE1 7RU, UKDepartment of Chemistry, University of Vermont, 82 University Place, Burlington, VT 05401, USAZirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated.http://www.mdpi.com/2304-6740/4/3/26hydrophosphinationdehydrocouplingprimary phosphinesfluorescence |
| spellingShingle | Christine A. Bange Neil T. Mucha Morgan E. Cousins Abigail C. Gehsmann Anna Singer Taylor Truax Lee J. Higham Rory Waterman Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine Inorganics hydrophosphination dehydrocoupling primary phosphines fluorescence |
| title | Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine |
| title_full | Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine |
| title_fullStr | Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine |
| title_full_unstemmed | Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine |
| title_short | Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine |
| title_sort | zirconium catalyzed alkene hydrophosphination and dehydrocoupling with an air stable fluorescent primary phosphine |
| topic | hydrophosphination dehydrocoupling primary phosphines fluorescence |
| url | http://www.mdpi.com/2304-6740/4/3/26 |
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