Fundamentals of reversible addition–fragmentation chain transfer (RAFT)

Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group in...

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Main Authors: Moad Catherine L., Moad Graeme
Format: Article
Language:English
Published: De Gruyter 2020-12-01
Series:Chemistry Teacher International
Subjects:
Online Access:https://doi.org/10.1515/cti-2020-0026
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author Moad Catherine L.
Moad Graeme
author_facet Moad Catherine L.
Moad Graeme
author_sort Moad Catherine L.
collection DOAJ
description Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group integrity and provides the ability to construct macromolecules with the intricate architectures and composition demanded by modern applications in medicine, electronics and nanotechnology. This paper provides a background to understanding the mechanism of RAFT polymerization and how this technique has evolved.
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spelling doaj.art-6c2113c4fc2440248f2272d7fcb94b8c2022-12-22T02:17:37ZengDe GruyterChemistry Teacher International2569-32632020-12-013231710.1515/cti-2020-0026Fundamentals of reversible addition–fragmentation chain transfer (RAFT)Moad Catherine L.0Moad Graeme1Highvale Secondary College, Glen Waverley, Victoria3150, AustraliaCSIRO Manufacturing, Clayton, Victoria3168, AustraliaRadical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group integrity and provides the ability to construct macromolecules with the intricate architectures and composition demanded by modern applications in medicine, electronics and nanotechnology. This paper provides a background to understanding the mechanism of RAFT polymerization and how this technique has evolved.https://doi.org/10.1515/cti-2020-0026addition–fragmentationradical polymerizationraftreversible-deactivation
spellingShingle Moad Catherine L.
Moad Graeme
Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
Chemistry Teacher International
addition–fragmentation
radical polymerization
raft
reversible-deactivation
title Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
title_full Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
title_fullStr Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
title_full_unstemmed Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
title_short Fundamentals of reversible addition–fragmentation chain transfer (RAFT)
title_sort fundamentals of reversible addition fragmentation chain transfer raft
topic addition–fragmentation
radical polymerization
raft
reversible-deactivation
url https://doi.org/10.1515/cti-2020-0026
work_keys_str_mv AT moadcatherinel fundamentalsofreversibleadditionfragmentationchaintransferraft
AT moadgraeme fundamentalsofreversibleadditionfragmentationchaintransferraft