A 17-year dataset of surface water fugacity of CO<sub>2</sub> along with calculated pH, aragonite saturation state and air–sea CO<sub>2</sub> fluxes in the northern Caribbean Sea

<p>A high-quality dataset of surface water fugacity of <span class="inline-formula">CO<sub>2</sub></span> (<span class="inline-formula"><i>f</i>CO<sub>2w</sub></span>)<span class="note-anchor" id="...

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Bibliographic Details
Main Authors: R. Wanninkhof, D. Pierrot, K. Sullivan, L. Barbero, J. Triñanes
Format: Article
Language:English
Published: Copernicus Publications 2020-07-01
Series:Earth System Science Data
Online Access:https://essd.copernicus.org/articles/12/1489/2020/essd-12-1489-2020.pdf
Description
Summary:<p>A high-quality dataset of surface water fugacity of <span class="inline-formula">CO<sub>2</sub></span> (<span class="inline-formula"><i>f</i>CO<sub>2w</sub></span>)<span class="note-anchor" id="fna_Ch1.Footn1"><a href="#fn_Ch1.Footn1"><sup>1</sup></a></span>, consisting of over a million observations, and derived products are presented for the northern Caribbean Sea, covering the time span from 2002 through 2018. Prior to installation of automated <span class="inline-formula"><i>p</i>CO<sub>2</sub></span> systems on cruise ships of Royal Caribbean International and subsidiaries, very limited surface water carbon data were available in this region. With this observational program, the northern Caribbean Sea has now become one of the best-sampled regions for <span class="inline-formula"><i>p</i>CO<sub>2</sub></span> of the world ocean. The dataset and derived quantities are binned and averaged on a 1<span class="inline-formula"><sup>∘</sup></span> monthly grid and are available at <span class="uri">http://accession.nodc.noaa.gov/0207749</span> (last access: 30 June 2020) (<a href="https://doi.org/10.25921/2swk-9w56">https://doi.org/10.25921/2swk-9w56</a>; Wanninkhof et al., 2019a). The derived quantities include total alkalinity (TA), acidity (pH), aragonite saturation state (<span class="inline-formula">Ω<sub>Ar</sub></span>) and air–sea <span class="inline-formula">CO<sub>2</sub></span> flux and cover the region from 15 to 28<span class="inline-formula"><sup>∘</sup></span>&thinsp;N and 88 to 62<span class="inline-formula"><sup>∘</sup></span>&thinsp;W. The gridded data and products are used for determination of status and trends of ocean acidification, for quantifying air–sea <span class="inline-formula">CO<sub>2</sub></span> fluxes and for ground-truthing models. Methodologies to derive the TA, pH and <span class="inline-formula">Ω<sub>Ar</sub></span> and to calculate the fluxes from <span class="inline-formula"><i>f</i>CO<sub>2w</sub></span> temperature and salinity are described.</p>
ISSN:1866-3508
1866-3516