Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition

The clean utilization of the CuCl residue containing chloride produced from zinc hydrometallurgy residue is very important for the recycle of valuable metals. A new method of microwave roasting under oxygen enriched condition was put forward to strengthen the process of dechlorination. It was demons...

Full description

Bibliographic Details
Main Authors: Zhanyong Guo, Ting Lei, Wei Li, Shaohua Ju, Jinhui Peng
Format: Article
Language:English
Published: De Gruyter 2016-05-01
Series:High Temperature Materials and Processes
Subjects:
Online Access:https://doi.org/10.1515/htmp-2014-0206
_version_ 1819131547845918720
author Zhanyong Guo
Ting Lei
Wei Li
Shaohua Ju
Jinhui Peng
author_facet Zhanyong Guo
Ting Lei
Wei Li
Shaohua Ju
Jinhui Peng
author_sort Zhanyong Guo
collection DOAJ
description The clean utilization of the CuCl residue containing chloride produced from zinc hydrometallurgy residue is very important for the recycle of valuable metals. A new method of microwave roasting under oxygen enriched condition was put forward to strengthen the process of dechlorination. It was demonstrated that the dechlorination rate of CuCl residue by microwave roasting was higher than that of conventional roasting by tubular resistance furnace under the same conditions (temperature, holding time and atmosphere). After roasting at a temperature of 450°C for 120 min under an oxygen flow rate of 150 mL/min in microwave field, the dechlorination rate of CuCl residue was as high as 97%, increasing 17% compared to that of conventional roasting using tubular resistance furnace. The characterizations of phase variation of CuCl residue in microwave field by means of X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) and Raman spectroscopy indicated that the process of dechlorination by microwave roasting under the oxygen enriched condition was much more efficient than conventional roasting.
first_indexed 2024-12-22T09:17:15Z
format Article
id doaj.art-6c4cec8db20247808286d374f7f541a4
institution Directory Open Access Journal
issn 0334-6455
2191-0324
language English
last_indexed 2024-12-22T09:17:15Z
publishDate 2016-05-01
publisher De Gruyter
record_format Article
series High Temperature Materials and Processes
spelling doaj.art-6c4cec8db20247808286d374f7f541a42022-12-21T18:31:17ZengDe GruyterHigh Temperature Materials and Processes0334-64552191-03242016-05-0135547948510.1515/htmp-2014-0206Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched ConditionZhanyong GuoTing Lei0Wei LiShaohua JuJinhui PengKunming Metallurgy College, Kunming, Yunnan 650093, ChinaThe clean utilization of the CuCl residue containing chloride produced from zinc hydrometallurgy residue is very important for the recycle of valuable metals. A new method of microwave roasting under oxygen enriched condition was put forward to strengthen the process of dechlorination. It was demonstrated that the dechlorination rate of CuCl residue by microwave roasting was higher than that of conventional roasting by tubular resistance furnace under the same conditions (temperature, holding time and atmosphere). After roasting at a temperature of 450°C for 120 min under an oxygen flow rate of 150 mL/min in microwave field, the dechlorination rate of CuCl residue was as high as 97%, increasing 17% compared to that of conventional roasting using tubular resistance furnace. The characterizations of phase variation of CuCl residue in microwave field by means of X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) and Raman spectroscopy indicated that the process of dechlorination by microwave roasting under the oxygen enriched condition was much more efficient than conventional roasting.https://doi.org/10.1515/htmp-2014-0206cucl residuezinc hydrometallurgymicrowave roastingdechlorination
spellingShingle Zhanyong Guo
Ting Lei
Wei Li
Shaohua Ju
Jinhui Peng
Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
High Temperature Materials and Processes
cucl residue
zinc hydrometallurgy
microwave roasting
dechlorination
title Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
title_full Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
title_fullStr Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
title_full_unstemmed Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
title_short Clean Utilization of CuCl Residue by Microwave Roasting under Oxygen-Enriched Condition
title_sort clean utilization of cucl residue by microwave roasting under oxygen enriched condition
topic cucl residue
zinc hydrometallurgy
microwave roasting
dechlorination
url https://doi.org/10.1515/htmp-2014-0206
work_keys_str_mv AT zhanyongguo cleanutilizationofcuclresiduebymicrowaveroastingunderoxygenenrichedcondition
AT tinglei cleanutilizationofcuclresiduebymicrowaveroastingunderoxygenenrichedcondition
AT weili cleanutilizationofcuclresiduebymicrowaveroastingunderoxygenenrichedcondition
AT shaohuaju cleanutilizationofcuclresiduebymicrowaveroastingunderoxygenenrichedcondition
AT jinhuipeng cleanutilizationofcuclresiduebymicrowaveroastingunderoxygenenrichedcondition