Introduction of ZnO, Sn, and P promoters in CuO/CeO2 catalysts for improved production of dimethyldichlorosilane in the Rochow-Müller reaction
Developing an efficiently supported Cu-based catalyst with promoters to substitute the existing non-supported Cu-based catalysts is highly desirable to the Rochow-Müller reaction. Using a simple ball-milling method and CeO2 support, we prepared a high-performance CuO-ZnO-P-Sn/CeO2 catalyst by integr...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2022-09-01
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| Series: | Resources Chemicals and Materials |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2772443322000265 |
| Summary: | Developing an efficiently supported Cu-based catalyst with promoters to substitute the existing non-supported Cu-based catalysts is highly desirable to the Rochow-Müller reaction. Using a simple ball-milling method and CeO2 support, we prepared a high-performance CuO-ZnO-P-Sn/CeO2 catalyst by integrating highly dispersed multicomponent promoters of ZnO, Sn, and P with the active component CuO. This catalyst shows a significantly enhanced dimethyldichlorosilane selectivity because these promoters can substantially increase the Cu+ content and the formation of an active CuxSi phase. This work provides a new approach to efficiently designing Cu-based catalysts for the Rochow-Müller reaction. |
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| ISSN: | 2772-4433 |