Modelling the Transport and Kinetics of Electroenzymes at the Electrode/Solution Interface
The solution phase transport and direct electrode kinetics of electro-enzymes are described in terms of a simple model in which the steady state reaction/diffusion equation for enzyme is solved subject to physically realistic boundary conditions. Two physically realizable situations are described: t...
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| Format: | Article |
| Language: | English |
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MDPI AG
2006-12-01
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| Series: | Sensors |
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| Online Access: | http://www.mdpi.com/1424-8220/6/12/1765/ |
| Summary: | The solution phase transport and direct electrode kinetics of electro-enzymes are described in terms of a simple model in which the steady state reaction/diffusion equation for enzyme is solved subject to physically realistic boundary conditions. Two physically realizable situations are described: the semi infinite and the membrane bounded case. Limiting expressions for the reaction flux are derived and the kinetic possibilities discussed geometrically in terms of kinetic case diagrams. |
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| ISSN: | 1424-8220 |