The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel

Calcium sulfide (CaS) inclusion with large and irregular shape is detrimental to the properties of steel. Understanding the shape and distribution of CaS inclusions in a continuous casting (CC) slab is of significance for improving the rolling properties. In this study, CaS inclusions were extracted...

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Main Authors: Jing Chen, Jing Zhang, Shaobo Zheng, Jieyu Zhang
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/17/3891
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author Jing Chen
Jing Zhang
Shaobo Zheng
Jieyu Zhang
author_facet Jing Chen
Jing Zhang
Shaobo Zheng
Jieyu Zhang
author_sort Jing Chen
collection DOAJ
description Calcium sulfide (CaS) inclusion with large and irregular shape is detrimental to the properties of steel. Understanding the shape and distribution of CaS inclusions in a continuous casting (CC) slab is of significance for improving the rolling properties. In this study, CaS inclusions were extracted from CC slab of Ni20Mn6 steel using the electrolytic extraction and investigated by scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX). The CaS inclusions morphologies vary with their locations in the CC slab and, thus, are classified into five categories. The thermodynamics calculated results showed that CaS inclusions precipitated at the end of solidification due to the microsegregation of sulfur and calcium in the interdendrite liquid and finally precipitated along the austenite grain boundary. The macrosegregation degree of solutes in different regions is one of the reasons that affect the size of CaS inclusion. The morphologies of CaS inclusion are affected by the solidification structure of slab and austenite grain boundary.
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spelling doaj.art-6c93805af2304854aa3f3314f5d61d312023-11-20T12:25:36ZengMDPI AGMaterials1996-19442020-09-011317389110.3390/ma13173891The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 SteelJing Chen0Jing Zhang1Shaobo Zheng2Jieyu Zhang3State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, ChinaState Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, ChinaState Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, ChinaState Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, ChinaCalcium sulfide (CaS) inclusion with large and irregular shape is detrimental to the properties of steel. Understanding the shape and distribution of CaS inclusions in a continuous casting (CC) slab is of significance for improving the rolling properties. In this study, CaS inclusions were extracted from CC slab of Ni20Mn6 steel using the electrolytic extraction and investigated by scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX). The CaS inclusions morphologies vary with their locations in the CC slab and, thus, are classified into five categories. The thermodynamics calculated results showed that CaS inclusions precipitated at the end of solidification due to the microsegregation of sulfur and calcium in the interdendrite liquid and finally precipitated along the austenite grain boundary. The macrosegregation degree of solutes in different regions is one of the reasons that affect the size of CaS inclusion. The morphologies of CaS inclusion are affected by the solidification structure of slab and austenite grain boundary.https://www.mdpi.com/1996-1944/13/17/3891calcium sulfide inclusionssolidification structuremacro and microsegregationcolumnar-to-equiaxed transition
spellingShingle Jing Chen
Jing Zhang
Shaobo Zheng
Jieyu Zhang
The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
Materials
calcium sulfide inclusions
solidification structure
macro and microsegregation
columnar-to-equiaxed transition
title The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
title_full The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
title_fullStr The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
title_full_unstemmed The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
title_short The Three-Dimensional Morphology and Distribution of CaS Inclusions in Continuous Casting Slab of Ni20Mn6 Steel
title_sort three dimensional morphology and distribution of cas inclusions in continuous casting slab of ni20mn6 steel
topic calcium sulfide inclusions
solidification structure
macro and microsegregation
columnar-to-equiaxed transition
url https://www.mdpi.com/1996-1944/13/17/3891
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