Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework

Two dimensional (2D) metal-organic frameworks have demonstrated unique photophysical properties compared to their bulk analogs. Here, the authors demonstrate that exfoliation of 2D MOFs can suppress interlayer exciton-related emission, allowing for modulation of the overall emission color and switch...

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Main Authors: Wei-Ming Liao, Jian-Hua Zhang, Shao-Yun Yin, He Lin, Xingmin Zhang, Jihong Wang, Hai-Ping Wang, Kai Wu, Zheng Wang, Ya-Nan Fan, Mei Pan, Cheng-Yong Su
Format: Article
Language:English
Published: Nature Portfolio 2018-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-04833-1
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author Wei-Ming Liao
Jian-Hua Zhang
Shao-Yun Yin
He Lin
Xingmin Zhang
Jihong Wang
Hai-Ping Wang
Kai Wu
Zheng Wang
Ya-Nan Fan
Mei Pan
Cheng-Yong Su
author_facet Wei-Ming Liao
Jian-Hua Zhang
Shao-Yun Yin
He Lin
Xingmin Zhang
Jihong Wang
Hai-Ping Wang
Kai Wu
Zheng Wang
Ya-Nan Fan
Mei Pan
Cheng-Yong Su
author_sort Wei-Ming Liao
collection DOAJ
description Two dimensional (2D) metal-organic frameworks have demonstrated unique photophysical properties compared to their bulk analogs. Here, the authors demonstrate that exfoliation of 2D MOFs can suppress interlayer exciton-related emission, allowing for modulation of the overall emission color and switching of optical memory states.
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spelling doaj.art-6cdada09d8b242afab8eebabae7153942022-12-21T19:09:29ZengNature PortfolioNature Communications2041-17232018-06-01911910.1038/s41467-018-04833-1Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic frameworkWei-Ming Liao0Jian-Hua Zhang1Shao-Yun Yin2He Lin3Xingmin Zhang4Jihong Wang5Hai-Ping Wang6Kai Wu7Zheng Wang8Ya-Nan Fan9Mei Pan10Cheng-Yong Su11MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityShanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of SciencesShanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of SciencesShanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of SciencesMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityMOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen UniversityTwo dimensional (2D) metal-organic frameworks have demonstrated unique photophysical properties compared to their bulk analogs. Here, the authors demonstrate that exfoliation of 2D MOFs can suppress interlayer exciton-related emission, allowing for modulation of the overall emission color and switching of optical memory states.https://doi.org/10.1038/s41467-018-04833-1
spellingShingle Wei-Ming Liao
Jian-Hua Zhang
Shao-Yun Yin
He Lin
Xingmin Zhang
Jihong Wang
Hai-Ping Wang
Kai Wu
Zheng Wang
Ya-Nan Fan
Mei Pan
Cheng-Yong Su
Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
Nature Communications
title Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
title_full Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
title_fullStr Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
title_full_unstemmed Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
title_short Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework
title_sort tailoring exciton and excimer emission in an exfoliated ultrathin 2d metal organic framework
url https://doi.org/10.1038/s41467-018-04833-1
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