The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr

In this article, the effects of an ionic nitriding treatment are analysed, together with deliberate variation of different thermal parameters associated with the destabilisation of austenite, on erosive wear resistance of white cast irons with 25% Cr. The methodology followed in this research was an...

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Main Authors: Alejandro González-Pociño, Florentino Alvarez-Antolin, Juan Asensio-Lozano
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/1/85
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author Alejandro González-Pociño
Florentino Alvarez-Antolin
Juan Asensio-Lozano
author_facet Alejandro González-Pociño
Florentino Alvarez-Antolin
Juan Asensio-Lozano
author_sort Alejandro González-Pociño
collection DOAJ
description In this article, the effects of an ionic nitriding treatment are analysed, together with deliberate variation of different thermal parameters associated with the destabilisation of austenite, on erosive wear resistance of white cast irons with 25% Cr. The methodology followed in this research was an experimental design, where six factors were analyzed by performing eight experiments. The thickness of the nitrided layer is much smaller than in white cast iron with lower percentages in Cr, never reaching 20 microns. The nitriding treatment entails considerable softening of the material underneath the nitriding layer. This softening behaviour becomes partially inhibited when the destabilisation temperature of austenite is 1100 °C and dwell times at such temperature are prolonged. This temperature seems to play a significant role in the solubilization of non-equilibrium eutectic carbides, formed during industrial solidification. The nitriding treatment leads to additional hardening, which, in these cases, favours a second destabilisation of austenite, with additional precipitation of secondary carbides and the transformation of retained austenite into martensite. Despite softening of the material, the nitriding treatment, together with air-cooling after destabilisation of the austenite, allows a noticeable increase in resistance to erosive wear.
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spelling doaj.art-6cdf4481a7b94576913c682ddd58e9cf2023-11-21T08:00:50ZengMDPI AGMetals2075-47012021-01-011118510.3390/met11010085The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% CrAlejandro González-Pociño0Florentino Alvarez-Antolin1Juan Asensio-Lozano2Materials Pro Group, Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica, Universidad de Oviedo, Independencia 13, 33004 Oviedo, SpainMaterials Pro Group, Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica, Universidad de Oviedo, Independencia 13, 33004 Oviedo, SpainMaterials Pro Group, Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica, Universidad de Oviedo, Independencia 13, 33004 Oviedo, SpainIn this article, the effects of an ionic nitriding treatment are analysed, together with deliberate variation of different thermal parameters associated with the destabilisation of austenite, on erosive wear resistance of white cast irons with 25% Cr. The methodology followed in this research was an experimental design, where six factors were analyzed by performing eight experiments. The thickness of the nitrided layer is much smaller than in white cast iron with lower percentages in Cr, never reaching 20 microns. The nitriding treatment entails considerable softening of the material underneath the nitriding layer. This softening behaviour becomes partially inhibited when the destabilisation temperature of austenite is 1100 °C and dwell times at such temperature are prolonged. This temperature seems to play a significant role in the solubilization of non-equilibrium eutectic carbides, formed during industrial solidification. The nitriding treatment leads to additional hardening, which, in these cases, favours a second destabilisation of austenite, with additional precipitation of secondary carbides and the transformation of retained austenite into martensite. Despite softening of the material, the nitriding treatment, together with air-cooling after destabilisation of the austenite, allows a noticeable increase in resistance to erosive wear.https://www.mdpi.com/2075-4701/11/1/85erosive wear resistancewhite cast irons containing 25% Crnitridingdestabilization of austenitesecondary carbides
spellingShingle Alejandro González-Pociño
Florentino Alvarez-Antolin
Juan Asensio-Lozano
The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
Metals
erosive wear resistance
white cast irons containing 25% Cr
nitriding
destabilization of austenite
secondary carbides
title The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
title_full The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
title_fullStr The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
title_full_unstemmed The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
title_short The Joint Effects of Nitriding and Parameters Related to the Destabilisation of Austenite on Wear Resistance in White Cast Iron with 25% Cr
title_sort joint effects of nitriding and parameters related to the destabilisation of austenite on wear resistance in white cast iron with 25 cr
topic erosive wear resistance
white cast irons containing 25% Cr
nitriding
destabilization of austenite
secondary carbides
url https://www.mdpi.com/2075-4701/11/1/85
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