Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes

Surface patterns with controllable features are constructed via the evaporation of an acetone solution of poly(methyl methacrylate) under the confinement of a copper tube. The effects of the dimensions of copper tube and the substrate temperature on the surface patterns are systematically studied. F...

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Main Authors: W. Sun, F. Q. Yang
Format: Article
Language:English
Published: Budapest University of Technology 2018-08-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0009043&mi=cd
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author W. Sun
F. Q. Yang
author_facet W. Sun
F. Q. Yang
author_sort W. Sun
collection DOAJ
description Surface patterns with controllable features are constructed via the evaporation of an acetone solution of poly(methyl methacrylate) under the confinement of a copper tube. The effects of the dimensions of copper tube and the substrate temperature on the surface patterns are systematically studied. For the substrate temperature in the range of 30 to 50 °C, the surface patterns are concentric rings consisting of waved rings and/or linked beads. The wavelength of the concentric rings decreases with the increase of the height of copper tube, and is dependent on the substrate temperature. At the substrate temperature of 20 °C, surface patterns are presented in wrinkling-like shape. At the substrate temperature of 10 °C, ‘breath figure’phenomenon occurs, and ‘hole network’ patterns are formed. A summary of the geometrical characteristics of the surface patterns is given, which can be used to better design and control evaporation-induced surface patterns.
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spelling doaj.art-6ce593e7465e40c58ceec656abfe30b22022-12-22T00:25:20ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2018-08-0112869971210.3144/expresspolymlett.2018.60Evaporation-assisted formation of surface patterns from polymer solutions via copper tubesW. SunF. Q. YangSurface patterns with controllable features are constructed via the evaporation of an acetone solution of poly(methyl methacrylate) under the confinement of a copper tube. The effects of the dimensions of copper tube and the substrate temperature on the surface patterns are systematically studied. For the substrate temperature in the range of 30 to 50 °C, the surface patterns are concentric rings consisting of waved rings and/or linked beads. The wavelength of the concentric rings decreases with the increase of the height of copper tube, and is dependent on the substrate temperature. At the substrate temperature of 20 °C, surface patterns are presented in wrinkling-like shape. At the substrate temperature of 10 °C, ‘breath figure’phenomenon occurs, and ‘hole network’ patterns are formed. A summary of the geometrical characteristics of the surface patterns is given, which can be used to better design and control evaporation-induced surface patterns.http://www.expresspolymlett.com/letolt.php?file=EPL-0009043&mi=cdCoatingsevaporationself-assemblysurface patterns
spellingShingle W. Sun
F. Q. Yang
Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
eXPRESS Polymer Letters
Coatings
evaporation
self-assembly
surface patterns
title Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
title_full Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
title_fullStr Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
title_full_unstemmed Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
title_short Evaporation-assisted formation of surface patterns from polymer solutions via copper tubes
title_sort evaporation assisted formation of surface patterns from polymer solutions via copper tubes
topic Coatings
evaporation
self-assembly
surface patterns
url http://www.expresspolymlett.com/letolt.php?file=EPL-0009043&mi=cd
work_keys_str_mv AT wsun evaporationassistedformationofsurfacepatternsfrompolymersolutionsviacoppertubes
AT fqyang evaporationassistedformationofsurfacepatternsfrompolymersolutionsviacoppertubes