Negative thermal expansion induced by intermetallic charge transfer
Suppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered d...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Taylor & Francis Group
2015-06-01
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| Series: | Science and Technology of Advanced Materials |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1088/1468-6996/16/3/034904 |
| _version_ | 1811225622422224896 |
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| author | Masaki Azuma Kengo Oka Koichiro Nabetani |
| author_facet | Masaki Azuma Kengo Oka Koichiro Nabetani |
| author_sort | Masaki Azuma |
| collection | DOAJ |
| description | Suppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered double perovskites SaCu3Fe4O12 and LaCu3Fe4−xMnxO12, as well as in Bi or Ni substituted BiNiO3. The last compound shows a colossal dilatometric linear thermal expansion coefficient exceeding −70 × 10−6 K−1 near room temperature, in the temperature range which can be controlled by substitution. |
| first_indexed | 2024-04-12T09:10:30Z |
| format | Article |
| id | doaj.art-6cf5f5fff39d411ea1370eeeeef22ea7 |
| institution | Directory Open Access Journal |
| issn | 1468-6996 1878-5514 |
| language | English |
| last_indexed | 2024-04-12T09:10:30Z |
| publishDate | 2015-06-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Science and Technology of Advanced Materials |
| spelling | doaj.art-6cf5f5fff39d411ea1370eeeeef22ea72022-12-22T03:38:59ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142015-06-0116310.1088/1468-6996/16/3/03490411661296Negative thermal expansion induced by intermetallic charge transferMasaki Azuma0Kengo Oka1Koichiro Nabetani2Tokyo Institute of TechnologyChuo UniversityTokyo Institute of TechnologySuppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered double perovskites SaCu3Fe4O12 and LaCu3Fe4−xMnxO12, as well as in Bi or Ni substituted BiNiO3. The last compound shows a colossal dilatometric linear thermal expansion coefficient exceeding −70 × 10−6 K−1 near room temperature, in the temperature range which can be controlled by substitution.http://dx.doi.org/10.1088/1468-6996/16/3/034904negative thermal expansionperovskitecharge transferx-ray diffraction |
| spellingShingle | Masaki Azuma Kengo Oka Koichiro Nabetani Negative thermal expansion induced by intermetallic charge transfer Science and Technology of Advanced Materials negative thermal expansion perovskite charge transfer x-ray diffraction |
| title | Negative thermal expansion induced by intermetallic charge transfer |
| title_full | Negative thermal expansion induced by intermetallic charge transfer |
| title_fullStr | Negative thermal expansion induced by intermetallic charge transfer |
| title_full_unstemmed | Negative thermal expansion induced by intermetallic charge transfer |
| title_short | Negative thermal expansion induced by intermetallic charge transfer |
| title_sort | negative thermal expansion induced by intermetallic charge transfer |
| topic | negative thermal expansion perovskite charge transfer x-ray diffraction |
| url | http://dx.doi.org/10.1088/1468-6996/16/3/034904 |
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