Complexes of Formaldehyde and α-Dicarbonyls with Hydroxylamine: FTIR Matrix Isolation and Theoretical Study

Complexes of Formaldehyde and α-Dicarbonyls with Hydroxylamine: FTIR Matrix Isolation and Theoretical Study

The interactions of formaldehyde (FA), glyoxal (Gly) and methylglyoxal (MGly) with hydroxylamine (HA) isolated in solid argon and nitrogen were studied using FTIR spectroscopy and ab initio methods. The spectra analysis indicates the formation of two types of hydrogen-bonded complexes between carbon...

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Bibliographic Details
Main Authors: Barbara Golec, Magdalena Sałdyka, Zofia Mielke
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Molecules
Subjects:
carbonyls
hydroxylamine
hydrogen bond
matrix isolation
vibrational spectroscopy
computational chemistry
Online Access:https://www.mdpi.com/1420-3049/26/4/1144

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