9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
In the title organic salt, C18H14N3O+·ClO4−·CH4O, there is a π–π stacking interaction between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid d...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808020606 |
| Summary: | In the title organic salt, C18H14N3O+·ClO4−·CH4O, there is a π–π stacking interaction between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C—H bond and a symmetry-related pyridine ring. There are classical N—H...O and O—H...N hydrogen bonds and non-classical C—H...O hydrogen bonds involving the cation, methanol solvent molecule and perchlorate anion. |
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| ISSN: | 1600-5368 |