9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate
In the title organic salt, C18H14N3O+·ClO4−·CH4O, there is a π–π stacking interaction between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid d...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808020606 |
| _version_ | 1819002751487574016 |
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| author | Chao Hou Shi Guo Zhang |
| author_facet | Chao Hou Shi Guo Zhang |
| author_sort | Chao Hou |
| collection | DOAJ |
| description | In the title organic salt, C18H14N3O+·ClO4−·CH4O, there is a π–π stacking interaction between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C—H bond and a symmetry-related pyridine ring. There are classical N—H...O and O—H...N hydrogen bonds and non-classical C—H...O hydrogen bonds involving the cation, methanol solvent molecule and perchlorate anion. |
| first_indexed | 2024-12-20T23:10:05Z |
| format | Article |
| id | doaj.art-6cfea7cb7c8043ac9e5b207d3b6a9336 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:10:05Z |
| publishDate | 2008-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6cfea7cb7c8043ac9e5b207d3b6a93362022-12-21T19:23:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648o1450o145010.1107/S16005368080206069-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvateChao HouShi Guo ZhangIn the title organic salt, C18H14N3O+·ClO4−·CH4O, there is a π–π stacking interaction between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid–centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C—H bond and a symmetry-related pyridine ring. There are classical N—H...O and O—H...N hydrogen bonds and non-classical C—H...O hydrogen bonds involving the cation, methanol solvent molecule and perchlorate anion.http://scripts.iucr.org/cgi-bin/paper?S1600536808020606 |
| spellingShingle | Chao Hou Shi Guo Zhang 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate Acta Crystallographica Section E |
| title | 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate |
| title_full | 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate |
| title_fullStr | 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate |
| title_full_unstemmed | 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate |
| title_short | 9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate |
| title_sort | 9 2 pyridylmethoxy 1 10 phenanthrolin 1 ium perchlorate methanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808020606 |
| work_keys_str_mv | AT chaohou 92pyridylmethoxy110phenanthrolin1iumperchloratemethanolsolvate AT shiguozhang 92pyridylmethoxy110phenanthrolin1iumperchloratemethanolsolvate |