H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability
Hybrid composite material was obtained through encapsulation of H3PW12O40 (PW) into HKUST-1 (Cu3(BTC)2, BTC=1,3,5-benzenetricarboxylic acid). The catalyst was characterized by various techniques including powder X-ray diffraction, Fourier transform infrared (FT-IR), scanning electron microscopy (SEM...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Slovenian Chemical Society
2016-04-01
|
| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/2236 |
| _version_ | 1819315574346350592 |
|---|---|
| author | Ezzat Rafiee Narges Nobakht |
| author_facet | Ezzat Rafiee Narges Nobakht |
| author_sort | Ezzat Rafiee |
| collection | DOAJ |
| description | Hybrid composite material was obtained through encapsulation of H3PW12O40 (PW) into HKUST-1 (Cu3(BTC)2, BTC=1,3,5-benzenetricarboxylic acid). The catalyst was characterized by various techniques including powder X-ray diffraction, Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), laser particle size analyzer. The acidity of the catalyst was determined by chemisorption of pyridine and potentiometric titration. This nano catalyst was successfully used for the synthesis of various β-keto enol ethers and was easily recycled and reused several times without significant loss of its activity. The presence of the PW in PW/HKUST-1 and reused PW/HKUST-1 structure, eliminating any doubt about collapse of the HKUST-1 after catalytic reaction and can be followed by FT-IR, XRD and SEM techniques. Brönsted and Lewis acidity of the PW/HKUST-1 catalyst was distinguished by studying the FT-IR. The strength and dispersion of the protons on PW/HKUST-1 was considerably high and active surface protons became more available for reactant. |
| first_indexed | 2024-12-24T10:02:16Z |
| format | Article |
| id | doaj.art-6d084782da664203b8568e61de532e56 |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-24T10:02:16Z |
| publishDate | 2016-04-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-6d084782da664203b8568e61de532e562022-12-21T17:01:00ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552016-04-0163230931610.17344/acsi.2016.2236341H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stabilityEzzat Rafiee0Narges Nobakht1Inorganic Chemistry Department, Faculty of Chemistry, Razi University, Kermanshah IranRazi UniversityHybrid composite material was obtained through encapsulation of H3PW12O40 (PW) into HKUST-1 (Cu3(BTC)2, BTC=1,3,5-benzenetricarboxylic acid). The catalyst was characterized by various techniques including powder X-ray diffraction, Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), laser particle size analyzer. The acidity of the catalyst was determined by chemisorption of pyridine and potentiometric titration. This nano catalyst was successfully used for the synthesis of various β-keto enol ethers and was easily recycled and reused several times without significant loss of its activity. The presence of the PW in PW/HKUST-1 and reused PW/HKUST-1 structure, eliminating any doubt about collapse of the HKUST-1 after catalytic reaction and can be followed by FT-IR, XRD and SEM techniques. Brönsted and Lewis acidity of the PW/HKUST-1 catalyst was distinguished by studying the FT-IR. The strength and dispersion of the protons on PW/HKUST-1 was considerably high and active surface protons became more available for reactant.https://journals.matheo.si/index.php/ACSi/article/view/2236Heteropoly acidMetal-organic frameworkβ-Keto enol ethersHeterogeneous catalystsHybrid composite material |
| spellingShingle | Ezzat Rafiee Narges Nobakht H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability Acta Chimica Slovenica Heteropoly acid Metal-organic framework β-Keto enol ethers Heterogeneous catalysts Hybrid composite material |
| title | H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability |
| title_full | H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability |
| title_fullStr | H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability |
| title_full_unstemmed | H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability |
| title_short | H3PW12O40 encapsulation by nanoporous metal organic framework HKUST-1: Synthesis, characterization, activity and stability |
| title_sort | h3pw12o40 encapsulation by nanoporous metal organic framework hkust 1 synthesis characterization activity and stability |
| topic | Heteropoly acid Metal-organic framework β-Keto enol ethers Heterogeneous catalysts Hybrid composite material |
| url | https://journals.matheo.si/index.php/ACSi/article/view/2236 |
| work_keys_str_mv | AT ezzatrafiee h3pw12o40encapsulationbynanoporousmetalorganicframeworkhkust1synthesischaracterizationactivityandstability AT nargesnobakht h3pw12o40encapsulationbynanoporousmetalorganicframeworkhkust1synthesischaracterizationactivityandstability |